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Merck
CN

341169

Sigma-Aldrich

酞菁锌

Dye content 97 %

别名:

酞菁 锌盐

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关于此项目

经验公式（希尔记法）:
C32H16N8Zn
化学文摘社编号:
14320-04-8
分子量:
577.91
Beilstein:
4121852
EC 号:
238-262-5
MDL编号:
MFCD00041955
UNSPSC代码:
12352103
PubChem化学物质编号:
24860701
NACRES:
NA.23

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组成

Dye content, 97%

质量水平

100

反应适用性

reagent type: catalyst
core: zinc

λmax

701 nm

轨道能量

HOMO 5.17 eV (CV)
LUMO 3.78 eV (CV)

OPV设备性能

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

SMILES字符串

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

PODBBOVVOGJETB-UHFFFAOYSA-N

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相关类别

一般描述

锌(II)酞菁（ZnPc）配合物具有光敏性。酞菁具有显著的π-π相互作用，易于形成H聚集体。

应用

锌酞菁在工业（催化剂、光电导体等）和生物医学（光动力疗法，PDT）中具有普遍应用。ZnPc可用于光氧化环己烷。 一项研究报告了用ZnPc对聚合物膜进行功能化。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000267004
0000267004
SHBQ3573
SHBP9359
MKCN2418

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Xiyou Li et al.
Journal of the American Chemical Society, 126(35), 10810-10811 (2004-09-02)
Light harvesting in photosynthetic antenna proteins involves a series of highly efficient ultrafast energy transfers between spectroscopically different populations of chlorophylls. Several strategies have recently been employed to mimic this natural energy transfer process, including polymers, dendrimers, and oligomeric porphyrin
Solvent effects on the photochemical and fluorescence properties of zinc phthalocyanine derivatives.
Ogunsipe A, et al.
Journal of Molecular Structure, 650(1), 131-140 (2003)
Peng Xu et al.
PloS one, 7(5), e37051-e37051 (2012-06-14)
Photodynamic therapy (PDT) is a promising therapeutic modality which uses a photosensitizer to capture visible light resulting in phototoxicity in the irradiated region. PDT has been used in a number of pathological indications, including tumor. A key desirable feature of
Polyamide nanofiber membranes functionalized with zinc phthalocyanines.
Goethals A, et al.
Journal of Applied Polymer Science, 131(13) (2014)
I M Tynga et al.
Journal of photochemistry and photobiology. B, Biology, 120, 171-176 (2012-12-26)
The development of curative techniques which are selective for neoplasms is one of the main focal areas in cancer research. The mechanism of cell damage due to Zinc phthalocyanine (ZnPcSmix)-mediated photodynamic therapy (PDT) in a breast cancer cell line (MCF-7)
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