341347
双(二异丙基氨基)氯膦
≥95.0%
别名:
氯化四异丙基磷酸二酰胺, 氯双（N,N-二异丙基）亚磷酰胺, 氯双（N,N-二异丙胺）膦
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关于此项目
线性分子式:
[[(CH3)2CH]2N]2PCl
化学文摘社编号:
分子量:
266.79
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Quality Level
assay
≥95.0%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling
mp
100-104 °C (lit.)
functional group
phosphine
SMILES string
CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
InChI
1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
InChI key
FEHUTHGOLLQBNW-UHFFFAOYSA-N
Application
双（二异丙基氨基）氯膦可用于合成 叔丁基四异丙基磷酰二胺配体，进行钯催化的 Buchwald–Hartwig 胺化反应。
还可用于合成：
还可用于合成：
- 无环 N-膦酰亚胺催化剂，用于选择性环氧化
- 硼基取代的亚甲基膦衍生物
Other Notes
含不定量的二异丙胺盐酸盐
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
相关内容
Phosphine Ligand Application Guide
Borylated methylenephosphonium salts: precursors of elusive boryl (phosphino) carbenes
Lavigne F, et al.
Journal of the American Chemical Society, 132(26), 8864-8865 (2010)
Novel N-phosphonio imine-catalyzed epoxidation reactions
Prieur D, et al.
Organic Letters, 10(11), 2291-2294 (2008)
Palladium?Catalysed Amination of Aryl?and Heteroaryl Halides Using tert?Butyl Tetraisopropylphosphorodiamidite as an Easily Accessible and Air?Stable Ligand
Roiban GD , et al.
European Journal of Organic Chemistry, 2014(10), 2070-2076 (2014)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 341347-5G | 04061833546871 |