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经验公式(希尔记法):
Ni3S2
化学文摘社编号:
分子量:
240.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
234-829-6
MDL number:
InChI key
YGHCWPXPAHSSNA-UHFFFAOYSA-N
InChI
1S/3Ni.2S
SMILES string
[Ni]=S=[Ni]=S=[Ni]
assay
99.7% trace metals basis
form
powder
reaction suitability
reagent type: catalyst
core: nickel
particle size
−200 mesh
density
5.8 g/mL at 25 °C (lit.)
application(s)
battery manufacturing
Quality Level
General description
Major phase is Ni3S2. Product may also include a small amount of sulfur-rich phase. Nickel Sulfide (Ni3S2) exists as a heazlewoodite mineral in nature. The structure of Ni3S2 is hombohedral. Raman spectral analysis of Ni3S2 has been reported.
Application
Nickel sulfide was implanted in mice, to induce the growth of malignant fibrous histiocytomas.
Packaging
Packaged in glass bottles
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Skin Sens. 1 - STOT RE 1 Inhalation
target_organs
Lungs
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
C Mayer et al.
Mutation research, 420(1-3), 85-98 (1998-12-05)
Carcinogenic nickel compounds are known to induce promutagenic DNA lesions such as DNA strand breaks and DNA adducts in cultured mammalian cells. In standard mutation assays, in contrast, they were found to be either inactive or weakly active. In our
Prosper M'Bemba-Meka et al.
The Science of the total environment, 369(1-3), 21-34 (2006-06-20)
When isolated human lymphocytes were treated in vitro either with various concentrations (0-2 mM) of soluble form of nickel subsulfide (Ni3S2) at 37 degrees C for 4 h or at various times (0-240 min), both concentration- and time-dependent effects of
Raman spectroscopy of nickel sulfide Ni3S2.
Cheng Z, et al.
The Journal of Physical Chemistry C, 111(49), 17997-18000 (2007)
Prosper M'Bemba-Meka et al.
Archives of toxicology, 81(2), 89-99 (2006-07-11)
Human peripheral lymphocytes from whole blood cultures were exposed to either soluble form of nickel carbonate hydroxide (NiCH) (0-60 microM), or of nickel subsulfide (Ni(3)S(2)) (0-120 microM), or of nickel oxide (NiO) (0-120 microM), or nickel sulfate (NiSO(4)) (0-120 microM)
Huaibo Ma et al.
Journal of the American Chemical Society, 133(15), 5644-5647 (2011-03-29)
The complex Tp(Ph,Me)NiS(2)CNMe(2) [Tp(Ph,Me) = hydrotris(3-phenyl-5-methyl-1-pyrazolyl)borate] features a bioinspired N(3)S(2) ligand set supporting a five-coordinate, trigonally distorted square-pyramidal geometry in the solid state. Spin crossover of Ni(II) was demonstrated by temperature-dependent X-ray crystallography and magnetic susceptibility measurements. The crystal lattice
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