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Merck
CN

343226

硫化镍

99.7% trace metals basis, −200 mesh

别名:

碱式硫化镍

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关于此项目

经验公式(希尔记法):
Ni3S2
化学文摘社编号:
分子量:
240.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
234-829-6
MDL number:
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InChI key

YGHCWPXPAHSSNA-UHFFFAOYSA-N

InChI

1S/3Ni.2S

SMILES string

[Ni]=S=[Ni]=S=[Ni]

assay

99.7% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: nickel

particle size

−200 mesh

density

5.8 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

Quality Level

General description

Major phase is Ni3S2. Product may also include a small amount of sulfur-rich phase. Nickel Sulfide (Ni3S2) exists as a heazlewoodite mineral in nature. The structure of Ni3S2 is hombohedral. Raman spectral analysis of Ni3S2 has been reported.

Application

Nickel sulfide was implanted in mice, to induce the growth of malignant fibrous histiocytomas.

Packaging

Packaged in glass bottles

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Lungs

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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C Mayer et al.
Mutation research, 420(1-3), 85-98 (1998-12-05)
Carcinogenic nickel compounds are known to induce promutagenic DNA lesions such as DNA strand breaks and DNA adducts in cultured mammalian cells. In standard mutation assays, in contrast, they were found to be either inactive or weakly active. In our
Prosper M'Bemba-Meka et al.
The Science of the total environment, 369(1-3), 21-34 (2006-06-20)
When isolated human lymphocytes were treated in vitro either with various concentrations (0-2 mM) of soluble form of nickel subsulfide (Ni3S2) at 37 degrees C for 4 h or at various times (0-240 min), both concentration- and time-dependent effects of
Raman spectroscopy of nickel sulfide Ni3S2.
Cheng Z, et al.
The Journal of Physical Chemistry C, 111(49), 17997-18000 (2007)
Prosper M'Bemba-Meka et al.
Archives of toxicology, 81(2), 89-99 (2006-07-11)
Human peripheral lymphocytes from whole blood cultures were exposed to either soluble form of nickel carbonate hydroxide (NiCH) (0-60 microM), or of nickel subsulfide (Ni(3)S(2)) (0-120 microM), or of nickel oxide (NiO) (0-120 microM), or nickel sulfate (NiSO(4)) (0-120 microM)
Huaibo Ma et al.
Journal of the American Chemical Society, 133(15), 5644-5647 (2011-03-29)
The complex Tp(Ph,Me)NiS(2)CNMe(2) [Tp(Ph,Me) = hydrotris(3-phenyl-5-methyl-1-pyrazolyl)borate] features a bioinspired N(3)S(2) ligand set supporting a five-coordinate, trigonally distorted square-pyramidal geometry in the solid state. Spin crossover of Ni(II) was demonstrated by temperature-dependent X-ray crystallography and magnetic susceptibility measurements. The crystal lattice

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