345482
(R)-(+)-2,2-二甲基-1,3-二氧戊环-4-羧酸甲酯
98%
别名:
α,β-异亚丙基-D-甘油酸甲酯, 2,3-O-异亚丙基-D-甘油酸甲酯, 甲基α,β-异亚丙基-D-甘油酸酯
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关于此项目
经验公式（希尔记法）:
C7H12O4
化学文摘社编号:
分子量:
160.17
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4292353
产品名称
(R)-(+)-2,2-二甲基-1,3-二氧戊环-4-羧酸甲酯, 98%
InChI
1S/C7H12O4/c1-7(2)10-4-5(11-7)6(8)9-3/h5H,4H2,1-3H3/t5-/m1/s1
SMILES string
COC(=O)[C@H]1COC(C)(C)O1
InChI key
DOWWCCDWPKGNGX-RXMQYKEDSA-N
assay
98%
form
liquid
optical activity
[α]20/D +8.5°, c = 1.5 in acetone
refractive index
n20/D 1.426 (lit.)
bp
70-75 °C/10 mmHg (lit.)
density
1.106 g/mL at 25 °C (lit.)
functional group
ester
ether
ketal
Quality Level
Application
Methyl (R)-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxylate may be used as a starting material to synthesize (2R)-[1-2H2]-glycerol, a probe to study the stereochemistry of glycerol metabolism in Streptomyces cattleya. It may also be used to synthesize organic building blocks like (R)-2,3-dihydroxy-3-methylbutyl toluene-p-sulfonate and (2S,8R)-2-amino-8-[(R) 2,2-dimethyl-1,3-dioxolan-4-yl]-8-oxooctanoic acid.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis of (24 R)-11a-(4-carboxybutyryloxy)-24, 25-dihydroxyvitamin D 3: a novel haptenic derivative producing antibodies of high affinity for (24 R)-24, 25-dihydroxyvitamin D 3.
Kobayashi N, et al.
J. Chem. Soc., Perkin Trans., 3, 269-275 (1994)
Synthesis of 2-amino-8-oxodecanoic acids (Aodas) present in natural hystone deacetylase inhibitors.
Rodriquez M, et al.
The Journal of Organic Chemistry, 71(1) (2006)
Biosynthesis of fluoroacetate and 4-fluorothreonine by Streptomyces cattleya. The stereochemical processing of glycerol.
Nieschalk J, et al.
Chemical Communications (Cambridge, England), 8, 799-800 (1997)
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