产品名称
5-苯基-1,3-环己二酮, 96%
InChI
1S/C12H12O2/c13-11-6-10(7-12(14)8-11)9-4-2-1-3-5-9/h1-5,10H,6-8H2
SMILES string
O=C1CC(CC(=O)C1)c2ccccc2
InChI key
UPPYKNLSSLIIAZ-UHFFFAOYSA-N
assay
96%
mp
188 °C (lit.)
functional group
ketone
phenyl
Application
5-Phenyl-1,3-cyclohexanedione may be used:
- in the synthesis of hexahydrobenzo[a]phenanthridin-4-one derivatives via condensation with N-arylmethylene-2-naphthylamines
- in the preparation of benzophenanthridine derivatives
- in the preparation of iodonium betaine
- in the synthesis of various 2H-pyrans by iodine-catalyzed reactions
General description
5-Phenyl-1,3-cyclohexanedione is a 1,3-diketone. Reaction of 5-phenyl-1,3-cyclohexanedione with N-substituted isatins in pyrindine has been investigated.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Efforts toward the synthesis of liphatic iodonium salts.
Dence JB and Roberts JD.
The Journal of Organic Chemistry, 33(3), 1251-1253 (1968)
Chunhui Dai et al.
Beilstein journal of organic chemistry, 8, 986-993 (2012-09-29)
A mild and practical synthesis of spirooxindole [1,3]oxazino derivatives from N-substituted isatins and 1,3-dicarbonyl compounds with pyridine derivatives is reported. The reactions provided good to excellent yields. Further exploration of the molecular diversity of these compounds is demonstrated through Diels-Alder
Reactions of bisazomethines of the naphtalene series with 1, 3-diketones.
Kozlov SN, et al.
Russ. J. Gen. Chem., 73(9), 1424-1440 (2009)
Synthesis of Benzo [a] phenanthridine Derivatives by Condensation of N-Arylmethylene-2-naphthylamines with 5-Phenyl-and 5-(p-Methoxyphenyl)-1, 3-cyclohexanediones.
Kozlov NG, et al.
Russ. J. Gen. Chem., 72(8), 1238-1242 (2002)
Iodine-Catalyzed One-Pot Synthesis of 2H-Pyrans by Domino Knoevenagel/6p-Electrocylization.
Jung EJ, et al.
Bull. Korean Chem. Soc., 30, 2833-2836 (2009)
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