InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Sn](Cl)(Cl)Cl
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
form
liquid
reaction suitability
core: tin, reagent type: Lewis acid, reagent type: catalyst
concentration
1.0 M in heptane
density
0.874 g/mL at 25 °C
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signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
24.8 °F - closed cup
flash_point_c
-4.0 °C - closed cup
法规信息
危险化学品
此项目有
Leo A Paquette et al.
The Journal of organic chemistry, 69(22), 7442-7447 (2004-10-23)
Tin tetrachloride-catalyzed glycosidation of persilylated nucleobases with acetate donor 6 in CH(2)Cl(2) solution followed by deprotection gave rise very predominantly to alpha-spironucleosides. These stereochemical assignments stem from the determination of NOE interactions and an X-ray crystallographic analysis of the latter
Isabelle Bonhoure et al.
Environmental science & technology, 37(10), 2184-2191 (2003-06-06)
In this study, the immobilization mechanisms of Sn(IV) onto calcium silicate hydrates (C-S-H) and hardened cement paste (HCP) have been investigated by combining wet chemistry experiments with X-ray absorption spectroscopy (XAS). Evidence is presented which demonstrates the formation of a
Yu-Jun Zhao et al.
Chemical communications (Cambridge, England), (12)(12), 1434-1436 (2008-03-14)
This communication describes a highly efficient intermolecular polyene cyclization method using steroidal acetals as the initiators to synthesize tetracyclic terpenoids; both good yields and good asymmetric induction were obtained.
Evangelina Repetto et al.
Bioorganic & medicinal chemistry, 17(7), 2703-2711 (2009-03-14)
Thiodisaccharides having beta-D-Galf or alpha-L-Araf units as non-reducing end have been synthesized by the SnCl(4)- or MoO(2)Cl(2)-promoted thioglycosylation of per-O-benzoyl-D-galactofuranose (1), its 1-O-acetyl analogue 4, or per-O-acetyl-alpha-L-arabinofuranose (16) with 6-thioglucose or 6-thiogalactose derivatives. After convenient removal of the protecting groups
Andreas T Messmer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(47), 14989-14995 (2012-10-04)
Determining the structure of reactive intermediates is the key to understanding reaction mechanisms. To access these structures, a method combining structural sensitivity and high time resolution is required. Here ultrafast polarization-dependent two-dimensional infrared (P2D-IR) spectroscopy is shown to be an
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