365483
(甲氧基羰基氨磺酰基)三乙基氢氧化铵 内盐
97%
别名:
伯吉斯试剂, 甲基 N-(三乙基氨磺酰基)氨基甲酸酯
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关于此项目
线性分子式:
CH3O2CNSO2N(C2H5)3
化学文摘社编号:
分子量:
238.30
Beilstein:
1432131
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
表单
powder
mp
76-79 °C (lit.)
官能团
amine
储存温度
−20°C
SMILES字符串
CC[N+](CC)(CC)S(=O)(=O)[N-]C(=O)OC
InChI
1S/C8H18N2O4S/c1-5-10(6-2,7-3)15(12,13)9-8(11)14-4/h5-7H2,1-4H3
InChI key
YSHOWEKUVWPFNR-UHFFFAOYSA-N
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应用
仲醇和叔醇、二醇、氨基醇、糖等化合物的强效脱水剂，包括与环氧化物的反应。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Synlett, 9, 1247-1247 (2003)
K C Nicolaou et al.
Journal of the American Chemical Society, 126(20), 6234-6235 (2004-05-20)
Although glycosylamines constitute an important group of carbohydrates from the standpoint of biology and medicine, methods for their synthesis typically lack substrate generality and/or result in variable stereoselectivity, especially in complex contexts. In this communication, we report an operationally simple
A A Nagel et al.
Journal of medicinal chemistry, 25(7), 881-884 (1982-07-01)
Ring contraction of the neutral oleandrose sugar in the 14-membered-ring macrolide antibiotic oleandomycin (2) has been accomplished using [(methoxycarbonyl)sulfamoyl]triethylammonium hydroxide inner salt (1). The product of this interesting rearrangement, after methanolic hydrolysis of the 2'-acetate, is the 11-acetyl-3-O-(3"-methoxy-4"-vinylfuranosyl)oleandomycin (12). The
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