392189
1-芘乙酸
97%
别名:
(1-芘基)乙酸
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关于此项目
经验公式（希尔记法）:
C18H12O2
化学文摘社编号:
分子量:
260.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C18H12O2/c19-16(20)10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)18(13)17(11)12/h1-9H,10H2,(H,19,20)
SMILES string
OC(=O)Cc1ccc2ccc3cccc4ccc1c2c34
InChI key
SDJCLYBBPUHKCD-UHFFFAOYSA-N
assay
97%
form
solid
mp
210-212 °C (dec.) (lit.)
functional group
carboxylic acid
Quality Level
General description
1-芘乙酸是一种带负电荷的芘衍生物。预期将其用作格氏试剂 和 n -丁基锂 （ n -BuLi）标准化滴定剂。
Application
1-芘乙酸适用于以下研究：
- N -（2-（甲硫基）乙基）-2-（芘-1-基）乙酰胺的合成，基于芘酰胺的 Pd 2 + 探针。
- 芘修饰的 β-环糊精的合成-环糊精。
- 使单壁碳纳米管字段效应晶体管（CNT FET）官能化。
- 作为表征酯官能化聚丙烯接枝率和反应性的试剂。
- 合成锯架式二钌四羰基络合物。
- 手性羧酸（±）-2-（1-芘基）丙酸的合成。
- 单壁碳纳米管的可逆非共价官能化。
- 肽核酸（PNA）探针的制备。
- 作为内引用化合物用于 HPLC-UV 法评估固相反应。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Pyrimidinone conjugates for the assignment of the absolute configuration of α-chiral carboxylic acids by 1H-NMR.
Murray RS, et al.
ARKIVOC (Gainesville, FL, United States), 11, 58-73 (2001)
Alex Manicardi et al.
Beilstein journal of organic chemistry, 10, 1495-1503 (2014-08-28)
Pyrene derivatives can be incorporated into nucleic acid analogs in order to obtain switchable probes or supramolecular architectures. In this paper, peptide nucleic acids (PNAs) containing 1 to 3 1-pyreneacetic acid units (PNA1-6) with a sequence with prevalence of pyrimidine
Murphy PJ.
Organophosphorus Reagents: A Practical Approach in Chemistry, 8-8 (2004)
Fushen Lu et al.
Langmuir : the ACS journal of surfaces and colloids, 26(10), 7561-7564 (2010-01-06)
An effective purification method for single-walled carbon nanotubes (SWNTs) based on a combination of oxidative acid treatment and reversible noncovalent functionalization with 1-pyreneacetic acid is reported. The functionalization was selective toward the nanotubes, allowing a nearly complete removal of residual
Ester functionalization of polypropylene via controlled decomposition of benzoyl peroxide during solid-state shear pulverization.
Diop MF and Torkelson JM.
Macromolecules, 46(19), 7834-7844 (2013)
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