392243
1-甲醛哌嗪
technical grade, 85%
别名:
1-哌嗪甲醛
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关于此项目
经验公式（希尔记法）:
C5H10N2O
化学文摘社编号:
分子量:
114.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
231-813-0
Beilstein/REAXYS Number:
110295
MDL number:
产品名称
1-甲醛哌嗪, technical grade, 85%
InChI key
MSSDTZLYNMFTKN-UHFFFAOYSA-N
InChI
1S/C5H10N2O/c8-5-7-3-1-6-2-4-7/h5-6H,1-4H2
SMILES string
[H]C(=O)N1CCNCC1
grade
technical grade
assay
85%
form
liquid
density
1.107 g/mL at 25 °C (lit.)
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Application
1-Formylpiperazine is sutable for use as a test compound in the kinetic study of the reaction of 4-nitrophenyl 2-thiophenecarboxylate with secondary alicyclic amines.
General description
1-Formylpiperazine, a secondary alicyclic amine is a piperazine derivative. Its synthesis has been reported. The kinetics of its reaction with O-aryl S-aryl dithiocarbonates has been studied. The IR and Raman spectra of 1-formylpiperazine have been investigated.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Kinetics and mechanism for the reaction of 4-nitrophenyl 2-thiophenecarboxylate with secondary alicyclic amines.
Um IH, et al.
Bull. Korean Chem. Soc., 23(3), 381-384 (2002)
Reactions of O-aryl S-aryl dithiocarbonates with secondary alicyclic amines in aqueous ethanol. Kinetics and mechanism.
Castro EA, et al.
Journal of Physical Organic Chemistry, 24(6), 466-473 (2011)
1-Formylpiperazine and related compounds.
Horrom BW, et al.
Journal of the American Chemical Society, 77(3), 753-754 (1955)
Gürkan Keşan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 1113-1120 (2013-10-29)
Infrared and Raman spectra of 1-formylpiperazine (1-fp) have been recorded in the region of 4000-50 cm(-1). The conformational analysis, optimized geometric parameters, normal mode frequencies and corresponding vibrational assignments of 1-fp (C5H10N2O) have been examined by means of Becke-3-Lee-Yang-Parr (B3LYP)
Gu-cai Li et al.
Die Pharmazie, 70(8), 511-514 (2015-09-19)
Five indolin-2-one derivatives bearing piperazinylbutyl side chains attached to the amide nitrogen were synthesized from 2-indolinone. 1-(4-Bromobutyl)-indolin-2-one was reacted with 1-piperazinecarboxaldehyde to form 1-(4-(4-formyl-1-piperazinyl)butyl)indolin-2-one (2). In the presence of H2SO4, the aldehyde moiety was removed from 1-(4-(4-formyl-1-piperazinyl)butyl)indolin-2-one and then 1-(4-(1-piperazinyl)butyl)indolin-2-one
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