398985
N-甲基-1,2-苯二胺
97%
别名:
1-N-甲基苯-1,2-二胺, 2(甲氨基)苯胺, 2-N-甲基苯-1,2-二胺, 2-氨基-N-甲基苯胺, N-甲基-1,2-二氨基苯, N-甲基-1,2-苯二胺, N-甲基邻二氨基苯, N-甲基邻苯二胺, N1-甲基-1,2-苯二胺
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.612 (lit.)
沸点
123-124 °C/10 mmHg (lit.)
mp
22 °C (lit.)
密度
1.075 g/mL at 25 °C (lit.)
官能团
amine
SMILES字符串
CNc1ccccc1N
InChI
1S/C7H10N2/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,8H2,1H3
InChI key
RPKCLSMBVQLWIN-UHFFFAOYSA-N
一般描述
N-甲基-1,2-苯二胺是一种 邻位 -二胺。N-甲基-1，2-苯二胺的原位生成重氮化阳离子曾用于玻碳电极的电化学修饰。
应用
N -甲基-1,2-苯二胺可用于以下研究：
- 一锅法合成 1-甲基-2-（杂）芳基苯并咪唑。
- 1-甲基-1 H -苯并咪唑-2（3 H ）-硫酮的制备。
- 血管紧张素 II 受体拮抗剂替米沙坦的全合成。
- 烯酮二硫代缩醛制备苯并咪唑类。
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Hizbullah Khan et al.
Acta crystallographica. Section E, Structure reports online, 64(Pt 6), o1141-o1141 (2008-01-01)
The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzene H atom and the benzene ring of a neighbouring mol-ecule, and by inter-molecular N-H⋯S
Recent developments in use of heteropolyacids, their salts and polyoxometalates in organic synthesis.
Heravi MM and Sadjadi S.
Journal of the Iranian Chemical Society, 6(1), 1-54 (2009)
A Sanjeev Kumar et al.
Beilstein journal of organic chemistry, 6, 25-25 (2010-05-27)
An efficient synthesis of the angiotensin II receptor antagonist Telmisartan (1) is presented involving a cross coupling of 4-formylphenylboronic acid 10 with 2-(2-bromophenyl)-4,4-dimethyl-2-oxazoline (11) as the key step (90% yield). The benzimidazole moiety 15 was constructed regioselectively via a reductive
Synthesis, 1273-1273 (1992)
Rodrigo Quezada et al.
Nanomaterials (Basel, Switzerland), 10(6) (2020-06-12)
Type of metal and metal-oxide NPs added to modify Thin-Film Composites Reverse Osmosis Membranes (TFC-RO) can alter their anti-biofouling properties by changing the dissolution process. The development of a mathematical model can facilitate the selection of these NPs. This work
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