429406
氯化铈(III)
AnhydroBeads™, −10 mesh, ≥99.99% trace metals basis
别名:
三氯化铈, 氯化亚铈
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关于此项目
经验公式（希尔记法）:
CeCl3
化学文摘社编号:
分子量:
246.48
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-227-8
MDL number:
Assay:
≥99.99% trace metals basis
Grade:
synthesis grade
Form:
beads
InChI key
VYLVYHXQOHJDJL-UHFFFAOYSA-K
InChI
1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
SMILES string
Cl[Ce](Cl)Cl
grade
synthesis grade
product line
AnhydroBeads™
assay
≥99.99% trace metals basis
form
beads
reaction suitability
core: cerium, reagent type: catalyst
impurities
≤100.0 ppm Trace Rare Earth Analysis
particle size
−10 mesh
mp
848 °C (lit.)
density
3.97 g/mL at 25 °C (lit.)
application(s)
electroplating
material synthesis precursor
perovskite solar cells
Quality Level
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General description
氯化铈（III）是一种无毒、耐水的路易斯酸催化剂，对各种化学转化具有高的区域性和化学选择性。它被广泛用作环境友好的酸性促进剂，用于许多合成有机反应，如 C-C 键形成反应、过渡金属催化脱氢和 C-O 双键还原。
Application
- 动态配体交换在铈（III）氧化化学中的作用：该研究利用氧化反应中的氯化铈（III），探索了铈的氧化还原化学，以理解其在各种化学转化中的潜力（JR Robinson et al., 2016）。
- 氯化铈（III）复合物引起的环烷醇的光催化C- C 键裂解和胺化：考察了用于C-C键裂解和胺化反应的氯化铈（III）复合物的光催化性质，重点介绍了其在有机合成中的潜力（JJ Guo et al., 2016）。
- 空气中六水合氯化铈的脱水、水解和氧化：研究了不同条件下水合形式氯化铈（III）的行为，该研究有助于理解其稳定性和反应（S Xue et al., 2017）。
Other Notes
打开安培瓶需要刻痕刀（Scoring knife）
Legal Information
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 2
ppe
dust mask type N95 (US), Eyeshields, Gloves
The use of anhydrous CeCl3 as a catalyst for the synthesis of 3-sulfenyl indoles
Claudio C. Silveira, et al.
Tetrahedron Letters, 51, 2014-2016 (2010)
Applications of CeCl3 as an Environmental Friendly Promoter in Organic Chemistry
Giuseppe Bartoli, et al.
Chemical Reviews, 110, 6104-6143 (2010)
Xiao, Z. Timberlake, J.W.
Tetrahedron, 54, 4211-4211 (1998)
Xiaoming Tao et al.
Organic letters, 15(1), 72-75 (2012-12-25)
Dynamic kinetic resolution of various α-amido-β-keto phosphonates via asymmetric hydrogenation proceeded efficiently to give the corresponding β-hydroxy-α-amido phosphonates in high diastereo- and enantioselectivities (up to 99:1 syn/anti, 99.8% ee). The addition of catalytic amounts of CeCl(3)·7H(2)O is necessary to achieve
Na Li et al.
Environmental toxicology, 28(6), 349-358 (2011-06-10)
To investigate the molecular mechanism of inflammatory response in the mouse liver caused by exposure to CeCl₃, we measured the liver indices, and cerium content, evaluated the liver histopathological section, detected serum biochemical parameters of liver function, and the immunoglobulin
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