43162
2-(二苯基膦基)乙胺
≥95.0% (GC), liquid
别名:
(2-氨基乙基)二苯基膦, 1-氨基-2-（二苯基膦基）乙烷
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关于此项目
经验公式（希尔记法）:
C14H16NP
化学文摘社编号:
分子量:
229.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Beilstein/REAXYS Number:
644931
产品名称
2-(二苯基膦基)乙胺, ≥95.0% (GC)
Quality Segment
assay
≥95.0% (GC)
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
functional group
phosphine
SMILES string
NCCP(c1ccccc1)c2ccccc2
InChI
1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2
InChI key
RXEPBCWNHKZECN-UHFFFAOYSA-N
General description
2-(二苯基膦基)乙胺是一种双齿结构的膦配体，磷原子提供两对孤对电子供金属离子配位。可用作反应剂，合成酰胺化合物选择性氢化反应的活性催化剂。它也被用作合成其他膦配体的前体。
Application
2-(二苯基膦基)乙胺可用作镍催化体系中的双齿配体，用于炔烃经还原[2+2]环加成合成环丁烯的反应。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Rhodium-P, O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions
Dalton Transactions, 39(8), 1929-1931 (2010)
A highly active catalyst for the hydrogenation of amides to alcohols and amines
Angewandte Chemie (International Edition in English), 50(44), 10377-10380 (2011)
Nickel-catalyzed reductive [2+ 2] cycloaddition of alkynes
Canellas S, et al.
Journal of the American Chemical Society, 140(50), 17349-17355 (2018)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 43162-1G | 04061832108377 |