440272
二氯二甲基硅烷
≥99.5%
别名:
DMDCS, 二甲基二氯硅烷
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关于此项目
线性分子式:
(CH3)2SiCl2
化学文摘社编号:
分子量:
129.06
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-901-0
Beilstein/REAXYS Number:
605287
MDL number:
Assay:
≥99.5%
Form:
liquid
InChI key
LIKFHECYJZWXFJ-UHFFFAOYSA-N
InChI
1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3
SMILES string
C[Si](C)(Cl)Cl
assay
≥99.5%
form
liquid
Quality Level
bp
70 °C (lit.)
mp
−76 °C (lit.)
storage temp.
2-8°C
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Application
用于与叔醇反应制备树脂键合硅氧烷。
用于合成光学活性柄型金属茂聚合催化剂的常用试剂。
Packaging
查看可回收的容器产品。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
33.8 °F - closed cup
flash_point_c
1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tetrahedron, 63, 299-299 (2007)
Cliff R Baar et al.
Journal of the American Chemical Society, 126(26), 8216-8231 (2004-07-01)
A series of enantiopure C1-symmetric metallocenes, [(SiMe2)2[eta5-C5H(CHMe2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-2, [(SiMe2)2[eta5-C5H(CHEt2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-6, and [(SiMe2)2[eta5-C5HCy2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-7 (Cy = cyclohexyl), zirconocene dichlorides that have an enantiopure methylneopentyl substituent on the "upper" cyclopentadienyl ligand, and diastereomerically pure precatalysts, [(SiMe2)2[eta5-C5H((S)-CHMeCy)(CHMe2)][eta5-C5H3]]ZrCl2, (S)-8a and (S)-8b, which have an
R Bos et al.
Microbiology (Reading, England), 142 ( Pt 9), 2355-2361 (1996-09-01)
Co-adhesion between oral microbial pairs (i.e. adhesion of a planktonic microorganism to a sessile organism adhering to a substratum surface) has been described as a highly specific interaction, mediated by stereochemical groups on the interacting microbial cell surfaces, and also
Takehiro Fukuzaki et al.
Organic letters, 4(17), 2877-2880 (2002-08-17)
[reaction: see text] Studies on the connection between the right and left segments of azadirachtin are described. The Ireland-Claisen rearrangement of Li-enolate of the modeled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield.
Raimundo Ho et al.
International journal of pharmaceutics, 387(1-2), 79-86 (2009-12-17)
The sensitivity of two techniques in tracking changes in surface energetics was investigated for a crystalline excipient, D-mannitol. Macroscopic crystals of D-mannitol were grown from saturated water solution by slow cooling, and sessile drop contact angle was employed to measure
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