445312
十六胺
98%
别名:
1-氨基十六烷, HAD, 鲸蜡胺
蒸汽压
<1 mmHg ( 20 °C)
质量水平
方案
98%
表单
solid
沸点
330 °C (lit.)
mp
43-45 °C (lit.)
官能团
amine
SMILES字符串
CCCCCCCCCCCCCCCCN
InChI
1S/C16H35N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h2-17H2,1H3
InChI key
FJLUATLTXUNBOT-UHFFFAOYSA-N
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应用
十六胺(HDA)可用于：
- 制备十六胺-三正辛基氧膦-三正辛基膦(HDA-TOPO-TOP)混合物，用于合成高发光强度单分散CdSe和CdSe/ZnS纳米晶体。
- 作为封端剂用于通过葡萄糖还原CuCl2合成不同形状的铜纳米晶体。
- 作为有机黏土中的亲有机烷胺物质，用于制备聚酰亚胺纳米复合材料。
- 与五氧化二钒(V2O5/HDA)形成膜，作为H+-离子敏感场效应晶体管(EGFET)装置的传感层。
- 作为还原剂和稳定剂用于十六胺修饰金和银纳米颗粒的制备，用于表面增强拉曼光谱(SERS)。
- 作为合成MCM-41类似物硅珠的模板。
- 与月桂酸共同用于制备具有磁性的钴(Co)纳米棒超晶格。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2
靶器官
Gastrointestinal tract,Liver,Immune system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
285.8 °F - closed cup
闪点(°C)
141 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
1-Hexadecylamine as both reducing agent and stabilizer to synthesize Au and Ag nanoparticles and their SERS application
Hou X, et al.
Journal of Nanoparticle Research, 13(5), 1929-1936 (2011)
Arnaud Glaria et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(3), 1169-1178 (2014-11-15)
The hydrogenolysis of [Cu2{(iPrN)2(CCH3)}2] in the presence of hexadecylamine (HDA) or tetradecylphosphonic acid (TDPA) in toluene leads to 6-9 nm copper nanocrystals. Solution NMR spectroscopy has been used to describe the nanoparticle surface chemistry during the dynamic phenomenon of air oxidation.
Jérémy Cure et al.
Langmuir : the ACS journal of surfaces and colloids, 31(4), 1362-1367 (2015-01-08)
Low size dispersity silver nanoparticles (ca. 6 nm) have been synthesized by the hydrogenolysis of silver amidinate in the presence of hexadecylamine. Combining NMR techniques with SERS and DFT modeling, it is possible to observe an original stabilization mechanism. Amidine
Synthesis and characterization of vanadium oxide/hexadecylamine membrane and its application as pH-EGFET sensor
Guerra EM and Mulato M
Journal of Sol-Gel Science and Technology, 52(3), 315-315 (2009)
Synthesis and magnetic properties of Co nanorod superlattices
Wetz F, et al.
Materials Science and Engineering, C, 27(5-8), 1162-1166 (2007)
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