Merck
CN

448273

Sigma-Aldrich

4-丙烯酰吗啉

97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor

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别名:
1-吗啉代丙-2-烯-1-酮, 1-(吗啉-4-基)丙烯酮, 4-丙烯酰基吗啉, 4-(1-氧代-2-丙烯基)吗啉, 丙烯酰吗啉
经验公式(希尔记法):
C7H11NO2
CAS号:
分子量:
141.17
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

97%

包含

1,000 ppm monomethyl ether hydroquinone as inhibitor

折射率

n20/D 1.512 (lit.)

mp

−35 °C (lit.)

密度

1.122 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES string

C=CC(=O)N1CCOCC1

InChI

1S/C7H11NO2/c1-2-7(9)8-3-5-10-6-4-8/h2H,1,3-6H2

InChI key

XLPJNCYCZORXHG-UHFFFAOYSA-N

一般描述

4-Acryloylmorpholine(ACMO) is an acrylate monomer widely used as a crosslinking agent in the polymer industry. It is used to form three-dimensional polymer networks to enhance the mechanical strength, stability, and durability of materials. The morpholine moiety in acryloylmorpholine imparts hydrophilicity to the molecule facilitating its applications in the field of adhesives, biocompatible coatings, and drug delivery systems. It is also used as a reactive monomer to synthesize hydrogels for drug delivery, photocurable materials for 3D bioprinting and display devices.

应用

4-Acryloylmorpholine can be used as a monomer:
  • To synthesize multiblock copolymers via RAFT polymerization. These functional block copolymers find application in the fields of medicine, energy, and nanotechnology.
  • To prepare organogel electrode frame via photopolymerization and cross-linking. This can be used to fabricate triboelectric nanogenerators with excellent transparency, stretchability, and interface adhesion.
  • For printing thermoplastic 3D tissue scaffolds. ACMO′s water solubility,and remarkably low viscosity, combined with surface oxygen inhibition, promoteswift liquid flow during high-speed open-air printing.

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral

储存分类代码

10 - Combustible liquids

WGK

WGK 2

闪点(°F)

259.7 °F - closed cup

闪点(°C)

126.5 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Rapid open-air digital light 3D printing of thermoplastic polymer
Shihong Deng, et al.
Advanced Materials, 31, 1903970-1903970 (2019)
Ultrafast RAFT polymerization: multiblock copolymers within minutes
Guillaume Gody, et al.
Polymer Chemistry: Introduction to an Indispensable Science, 6, 1502-1511 (2015)
Organ gel electrode enables highly transparent and stretchable triboelectric nanogenerators of high power density for robust and reliable energy harvesting
Titao Jing, et al.
Nano Energy, 78, 105373-105373 (2020)
Hafiz Awais Nawaz et al.
Journal of materials chemistry. B, 9(9), 2295-2307 (2021-02-23)
Injectable gelatine-based hydrogels are valuable tools for drug and cell delivery due to their extracellular matrix-like properties that can be adjusted by the degree of cross-linking. We have established anhydride-containing oligomers for the cross-linking of gelatine via anhydride-amine-conjugation. So far
Kalyan Ramesh et al.
Materials (Basel, Switzerland), 13(17) (2020-08-28)
Owing to their unique topology and physical properties, micelles based on miktoarm amphiphilic star block copolymers play an important role in the biomedical field for drug delivery. Herein, we developed a series of AB2-type poly(D,L-lactide-co-glycolide)-b-poly(N-acryloyl morpholine) (PLGA-b-PNAM2) miktoarm star block

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