蒸汽密度
3.7 (vs air)
质量水平
蒸汽压
0.26 mmHg ( 25 °C)
方案
98%
表单
liquid
自燃温度
899 °F
折射率
n20/D 1.572 (lit.)
沸点
199-200 °C (lit.)
89-90 °C/11 mmHg (lit.)
mp
−28 °C (lit.)
溶解性
H2O: slightly soluble
密度
1.008 g/mL at 25 °C (lit.)
SMILES字符串
Cc1ccccc1N
InChI
1S/C7H9N/c1-6-4-2-3-5-7(6)8/h2-5H,8H2,1H3
InChI key
RNVCVTLRINQCPJ-UHFFFAOYSA-N
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一般描述
o-Toluidine undergoes chemically oxidative polymerization with aniline in the presence of ammonium persulfate as an oxidant in HCl medium.
应用
o-Toluidine was used as a precursor in the synthesis of poly(o-toluidine) and copper nanoparticle composite material.
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
185.0 °F - closed cup
闪点(°C)
85 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Oxidative copolymers of aniline with o-toluidine: Their structure and thermal properties.
Huang M-R, et al.
Journal of Applied Polymer Science, 81(8), 1838-1847 (2001)
In situ synthesis of copper nanoparticles and poly (< i> o</i>-toluidine): A metal-polymer composite material.
Mallick K, et al.
Eur. Polymer J., 42(3), 670-675 (2006)
Hun-Je Jo et al.
Chemosphere, 70(6), 949-957 (2007-09-26)
In this study, major toxicants in pigment wastewaters (i.e. raw wastewater and effluent) were determined by toxicity identification evaluations (TIEs), and changes in their toxicities due to combined gamma-ray (gamma-ray) and ozone treatments were evaluated. From TIE results using Daphnia
Tania Carreón et al.
Occupational and environmental medicine, 67(5), 348-350 (2009-11-04)
In 1991, the US National Institute for Occupational Safety and Health (NIOSH) reported an increased bladder cancer risk in a cohort of 1749 workers potentially exposed to o-toluidine and aniline at a chemical manufacturing plant. As additional information showed that
Ivo Kalkman et al.
Physical chemistry chemical physics : PCCP, 11(21), 4311-4318 (2009-05-22)
The rotationally resolved spectrum of the o-toluidine S(1)<-- S(0) origin was measured using laser induced fluorescence spectroscopy. From the resulting spectrum torsional barriers to internal rotation of the methyl group were derived, which resulted in S(0) state values of V(3)
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