469505
(R)-2-(Boc-氨基)-1-丙醇
98%, optical purity ee: 98% (GLC)
别名:
(R)-(+)-2-(叔丁氧羰基氨基)-1-丙醇, N-Boc-D-丙氨醇
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关于此项目
线性分子式:
CH3CH[NHCO2C(CH3)3]CH2OH
化学文摘社编号:
分子量:
175.23
UNSPSC Code:
12352200
PubChem Substance ID:
MDL number:
产品名称
(R)-2-(Boc-氨基)-1-丙醇, 98%, optical purity ee: 98% (GLC)
InChI
1S/C8H17NO3/c1-6(5-10)9-7(11)12-8(2,3)4/h6,10H,5H2,1-4H3,(H,9,11)/t6-/m1/s1
SMILES string
C[C@H](CO)NC(=O)OC(C)(C)C
InChI key
PDAFIZPRSXHMCO-ZCFIWIBFSA-N
assay
98%
form
solid
optical activity
[α]20/D +11°, c = 1 in chloroform
optical purity
ee: 98% (GLC)
reaction suitability
reaction type: Boc solid-phase peptide synthesis
mp
58-61 °C (lit.)
application(s)
peptide synthesis
Application
用于合成抗血栓 3-哌啶甲酰胺。
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Anna Said Stålsmeden et al.
Organic & biomolecular chemistry, 18(10), 1957-1967 (2020-02-27)
1,4- and 1,5-Disubstituted triazole amino acid monomers have gained increasing interest among peptidic foldamers, as they are easily prepared via Cu- and Ru-catalyzed click reactions, with the potential for side chain variation. While the latter is key to their applicability
X Zheng et al.
Chirality, 7(2), 90-95 (1995-01-01)
The stereoisomers of alpha,alpha'-bis[3-(N,N-diethylcarbamoyl)-piperidino]-p-xylene (1) were synthesized. Rac ethyl nipecotate was resolved by diastereomeric (-)-D- and (+)-L-tartrate salt formation. The enantiomeric esters were hydrolyzed to the corresponding nipecotic acids, which were then converted into t-BOC derivatives. Treatment of the latter
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