481378
烯丙基氯
别名:
3-氯-1-丙烯, 氯丙烯
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线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
分子量:
76.52
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-457-6
Beilstein/REAXYS Number:
635704
MDL number:
InChI key
OSDWBNJEKMUWAV-UHFFFAOYSA-N
InChI
1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
SMILES string
ClCC=C
vapor density
2.6 (vs air)
vapor pressure
20.58 psi ( 55 °C), 5.71 psi ( 20 °C)
assay
98.0% (returnable containers)
expl. lim.
11.2 %
refractive index
n20/D 1.414 (lit.)
bp
44-46 °C (lit.)
mp
−130 °C (lit.)
density
0.939 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Packaging
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Nervous system,Liver,Kidney, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-25.6 °F
flash_point_c
-32 °C
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
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Shin-ichi Ikeda et al.
Chemical communications (Cambridge, England), (4)(4), 457-459 (2006-02-24)
The Ni-catalyzed coupling of allyl chlorides and enynes has been developed; the cyclization of enynes was triggered by the addition of pi-allylnickel species to the alkyne part, followed by the incorporation of the alkene part.
Yan-Bo Yu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(46), 14643-14648 (2012-10-12)
Simply id(all)ylic: a copper- and phosphine-ligand-free Pd-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides and the reaction mechanism are described. The simple catalytic system, broad substrate scope, and excellent functional-group compatibility of this protocol provides a useful and facile
B M de Rooij et al.
Drug metabolism and disposition: the biological fate of chemicals, 24(7), 765-772 (1996-07-01)
Allyl chloride (AC) is used as intermediate in the synthesis of epichlorohydrin (ECH). We investigated the biotransformation of AC in rats to select potential urinary biomarkers of exposure. For this purpose, we developed analytical methods to measure different selected urinary
Justin M Chalker et al.
Chemical communications (Cambridge, England), (25)(25), 3714-3716 (2009-06-27)
Multiple, complementary methods are reported for the chemical conversion of cysteine to S-allyl cysteine on protein surfaces, a useful transformation for the exploration of olefin metathesis on proteins.
Kai Abersfelder et al.
Journal of the American Chemical Society, 130(12), 4114-4121 (2008-03-04)
The rearrangements of (chlorosilyl)disilenes R2(Cl)Si-(Tip)Si=SiTip2 (5a,b: Tip = 2,4,6-iPr3C6H2, a: R = Me, b: R = Ph) quantitatively yield the isomeric chlorocyclotrisilanes (6a,b). The disilene precursors 5a,b are, in turn, accessible from the reactions of the disilenide Tip2Si=Si(Tip)Li (1), that
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