49362
戊烯二酸二甲酯
≥95.0% (GC)
别名:
二甲基 2-戊烯酸酯
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关于此项目
线性分子式:
CH3OOCCH2CH=CHCOOCH3
化学文摘社编号:
分子量:
158.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1724169
Assay:
≥95.0% (GC)
assay
≥95.0% (GC)
refractive index
n20/D 1.452
density
1.124 g/mL at 20 °C (lit.)
functional group
ester
SMILES string
COC(=O)C\C=C\C(=O)OC
InChI
1S/C7H10O4/c1-10-6(8)4-3-5-7(9)11-2/h3-4H,5H2,1-2H3/b4-3+
InChI key
SKCGFFOFYXLNCG-ONEGZZNKSA-N
General description
Dimethyl glutaconate, also known as dimethyl 2-pentenoate, is a diester. It reacts with salicaldehyde in the presence of piperidine to form a coumarin-fused electron deficient diene.
Application
Dimethyl glutaconate may be used in the synthesis of:
- dimethyl 3-[(Z)-1-propenyl]glutarate
- phenanthridinone derivatives
- substituted benzenes
Other Notes
组成：~83% 反式 + ~17% 顺式
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 3
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
A convenient method for the preparation of 3-substituted glutarate diesters.
Leotta III, et al.
The Journal of Organic Chemistry, 59(7), 1946-1946 (1994)
Electron Deficient Dienes. 2. One Step Synthesis of a Coumarin-Fused Electron Deficient Diene and its Inverse Electron Demand Diels-Alder Reactions with Enamines.
Bodwell GJ, et al.
Synlett, 4, 477-479 (1999)
One-Pot Synthesis of Phenanthridinones by Using a Base-Catalyzed/Promoted Bicyclization of a, ?-Unsaturated Carbonyl Compounds with Dimethyl Glutaconate.
Li L, et al.
European Journal of Organic Chemistry, 2015(22), 4892- 4899 (2015)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 49362-100ML | 04061837500176 |