49800
D -(+)-甘油醛
≥98.0% (HPLC)
别名:
(2R)-2,3-Dihydroxypropanal, Triose
应用
D-(+)-甘油醛可用作合成以下物质的反应物：
- (S)-高苯丙氨酸，通过胺和α-羟醛偶联生成的3-氨基-1,2-二醇的钌氧化制备。
- β- 和γ-联烯醇，通过金属催化环化制备。联烯醇是制备对映体纯的二氢吡喃和四氢噁英（tetrahydrooxepine）的关键前体。
- 异亚丙基D-甘油醛中间体，其控制前列腺素（PGE1）的总合成中的手性。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves
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BMC complementary and alternative medicine, 17(1), 137-137 (2017-03-06)
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Metal-Catalyzed Cyclization of β-and γ-Allenols Derived from d-Glyceraldehyde- Synthesis of Enantiopure Dihydropyrans and Tetrahydrooxepines: An Experimental and Theoretical Study
Alcaide BL
Chemistry?A European Journal , 15(36), 9127-9138 (2009)
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