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Merck
CN

51053

Sigma-Aldrich

1-乙基-3-甲基咪唑乙酸酯

≥95.0% (HPLC)

别名:

EMIM Ac

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关于此项目

经验公式(希尔记法):
C8H14N2O2
化学文摘社编号:
分子量:
170.21
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

≥95.0% (HPLC)

来源

Switzerland origin

mp

>30 °C (product can occur as an undercooled melt)

密度

1.101 g/cm3 at 20 °C

SMILES字符串

CC([O-])=O.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.C2H4O2/c1-3-8-5-4-7(2)6-8;1-2(3)4/h4-6H,3H2,1-2H3;1H3,(H,3,4)/q+1;/p-1

InChI key

XIYUIMLQTKODPS-UHFFFAOYSA-M

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一般描述

1-乙基-3-甲基咪唑乙酸酯([EMIM][Ac])是一种与水混溶的环保型咪唑离子液体。它显示出良好的纤维素溶解能力。[·EMIM Ac]对梭菌恶臭假单胞菌生长影响的研究显示出类似激素的作用。据报道,无机盐的加入提高了其离子性。我们还对纤维素在活性炭中的热稳定性进行了研究。

应用

1-乙基-3-甲基咪唑乙酸盐适用于纤维素与酰氯、三苯甲基氯和甲苯磺酰氯的均相转化中作为纤维素溶剂。它可用作合成接枝有聚苯乙烯(淀粉-g-PS)的淀粉和环境友好纤维素膜的共聚物的溶剂。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Skin Irrit. 2 - Skin Sens. 1B

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

327.2 °F - closed cup

闪点(°C)

164 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Yongjun Men et al.
Carbohydrate polymers, 121, 348-354 (2015-02-11)
The copolymer of starch grafted with polystyrene (starch-g-PS) was synthesized with high grafting percentage by utilizing the ionic liquid 1-ethyl-3-methylimidazolium acetate ([EMIM]Ac) as solvent and potassium persulfate as initiator. The effect of various parameters upon the polymerization were studied including:
JinHui Pang et al.
Carbohydrate polymers, 121, 71-78 (2015-02-11)
With the serious "white pollution" resulted from the non-biodegradable plastic films, considerable attention has been directed toward the development of renewable and biodegradable cellulose-based film materials as substitutes of petroleum-derived materials. In this study, environmentally friendly cellulose films were successfully
Anne Michud et al.
Carbohydrate polymers, 117, 355-363 (2014-12-17)
The thermal stability of cellulose in the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate, [emim]OAc was investigated. For this purpose, Eucalyptus urugrandis prehydrolysis kraft pulp was first dissolved in [emim]OAc by means of a vertical kneader and then stored at three different
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Bioactive materials, 5(3), 577-583 (2020-05-15)
Chitosan is a nature-based polymer with low toxicity, excellent biocompatibility and biodegradability. However, the intractable solubility of chitosan in water and most conventional solvents hampers its biomedical applications. Following the dissolution method for dissolving chitosan in plain water developed by

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