514381
氯化钛(III)
≥99.995% trace metals basis
别名:
三氯化钛
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关于此项目
线性分子式:
TiCl3
化学文摘社编号:
分子量:
154.23
UNSPSC Code:
26111700
PubChem Substance ID:
EC Number:
231-728-9
MDL number:
InChI key
YONPGGFAJWQGJC-UHFFFAOYSA-K
InChI
1S/3ClH.Ti/h3*1H;/q;;;+3/p-3
SMILES string
Cl[Ti](Cl)Cl
assay
≥99.995% trace metals basis
form
crystalline
reaction suitability
reagent type: catalyst
core: titanium
mp
440 °C (dec.) (lit.)
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Application
用于气相形成具有超细粒度的金属间化合物。
signalword
Danger
hcodes
Hazard Classifications
Pyr. Sol. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating
H A Akers et al.
Analytical biochemistry, 154(2), 559-563 (1986-05-01)
Thirteen model alpha-ketocarboxylic acids and alpha-dicarbonyl compounds have been observed to be reduced by titanium(III) chloride. The products of these reactions were shown by melting (boiling) points, mixed melting points, derivatives, refractive indices, infrared, and NMR comparisons with authentic compounds
Gema Ruano et al.
The Journal of organic chemistry, 68(5), 2024-2027 (2003-03-01)
Enantiomerically pure N-substituted epoxyalkene-2-azetidinones reacted with titanocene monochloride to give stereospecifically polyfunctionalized bicyclic beta-lactams. Four isomeric epoxyaldehydes 2 reacted with TiCp2Cl to give exclusively the respective carbacephams 7 while under the same reaction conditions the epoxyesters 1, which are more
Palaniappan Kulanthaivel et al.
Drug metabolism and disposition: the biological fate of chemicals, 32(9), 966-972 (2004-08-21)
Phase I oxidative metabolism of nitrogen-containing drug molecules to their corresponding N-oxides is a common occurrence. There are instances where liquid chromatography/tandem mass spectometry techniques are inadequate to distinguish this pathway from other oxidation processes, including C-hydroxylations and other heteroatom
Jun-ichi Matsuo et al.
Organic letters, 12(14), 3266-3268 (2010-06-24)
N-p-Toluenesulfonyl (Ts) aldimines reacted with 3-ethoxycyclobutanones by catalysis of titanium(IV) chloride to afford 2,3-di- or 2,3,3-trisubstituted N-Ts-2,3-dihydro-4-pyridones. Synthesis of (+/-)-bremazocine was efficiently accomplished by using this method.
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