516414
1-(苯磺酰)-3-吲哚甲醛
97%
别名:
1-(Benzenesulfonyl)indole-3-carboxaldehyde, 1-(Phenylsulfonyl)-3-formylindole, NSC 628191
方案
97%
表单
solid
mp
157-161 °C (lit.)
SMILES字符串
[H]C(=O)c1cn(c2ccccc12)S(=O)(=O)c3ccccc3
InChI
1S/C15H11NO3S/c17-11-12-10-16(15-9-5-4-8-14(12)15)20(18,19)13-6-2-1-3-7-13/h1-11H
InChI key
ZLARITBCJILRBL-UHFFFAOYSA-N
应用
Reactant for:
Reactant for preparation of:
- Peterson olefination
Reactant for preparation of:
- Antifungal agents
- Potential topoisomerase II inhibitors
- Anti-inflammatory, analgesic and anticonvulsant agents
- Bacteriorhodopsin analogs
- Antitumor agents
- Antitubercular agents
- Inhibitors of human dUTPase and UNG2
- Uracil DNA glycosylase inhibitor
- Anti-HIV and anti-tumor β-carbolines
Ming-Zhi Zhang et al.
European journal of medicinal chemistry, 53, 283-291 (2012-05-09)
A simple and efficient synthetic protocol for 5-(3-indolyl)-oxazoles has been developed and further used to synthesize a series of novel analogues of natural product pimprinine. All new compounds were identified by (1)H NMR, high resolution mass spectrometry, and the structures
Bo Cheng et al.
Organic letters, 12(16), 3622-3625 (2010-08-14)
A concise synthesis of (+/-)-pseudotabersonine from commercially available 1-(phenylsulfonyl)-3-indolecarboxaldehyde has been accomplished. This synthesis features the convergent assembly of a key intermediate via a stepwise variant of a Mannich-type multicomponent coupling process, a double ring-closing metathesis, and a one-pot deprotection/cyclization
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