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Merck
CN

520748

Sigma-Aldrich

氧化钯(II)

99.97% trace metals basis

别名:

一氧化钯, 氧化钯

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关于此项目

经验公式(希尔记法):
OPd
化学文摘社编号:
分子量:
122.42
EC 号:
MDL编号:
UNSPSC代码:
12352303
PubChem化学物质编号:
NACRES:
NA.23
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质量水平

方案

99.97% trace metals basis

表单

powder and chunks

组成

Pd, 85-87%

反应适用性

reagent type: catalyst
core: palladium

mp

870 °C (lit.)

密度

8.7 g/mL at 25 °C (lit.)

SMILES字符串

O=[Pd]

InChI

1S/O.Pd

InChI key

HBEQXAKJSGXAIQ-UHFFFAOYSA-N

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一般描述

氧化钯(II)(PdO)是一种p型半导体,其带隙宽度在2.2至-2.7 eV之间。它是一种使用广泛的高效催化剂,用于烃的氧化反应和气体传感器的制造。

应用

二氧化铈 负载的氧化钯(II)可用作草酸盐臭氧化的催化剂, 用于改善受污染的水中难分解有机物质的 降解。 PdO 为 臭氧降解为表面原子氧提供活性位点。 它可作为 WO3催化剂上的助催化剂进行醇的部分氧化。

象形图

Flame over circle

警示用语:

Danger

危险声明

危险分类

Ox. Sol. 2

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Young Tack Lee et al.
Nanotechnology, 21(16), 165503-165503 (2010-03-30)
We report on a novel method for the fabrication of highly sensitive hydrogen gas sensors based on palladium oxide thin films and have investigated their hydrogen sensing properties and nanostructures. To our knowledge, this is the first report on the
Hua-Qing Yang et al.
Journal of computational chemistry, 32(16), 3440-3455 (2011-09-16)
The gas-phase reaction mechanism between palladium monoxide and methane has been theoretically investigated on the singlet and triplet state potential energy surfaces (PESs) at the CCSD(T)/AVTZ//B3LYP/6-311+G(2d, 2p), SDD level. The major reaction channel leads to the products PdCH(2) + H(2)O
Y J Huang et al.
Chemosphere, 39(13), 2279-2287 (1999-11-27)
Experimentally, decomposition of NO on the alkalized Pd/Al2O3 catalyst is remarkably enhanced at 825-1000 K. The enhancement in N2 yield may be due to the additional basic sites on the alkalized catalyst that can trap NO molecules. However, at T
Hongkun He et al.
Molecules (Basel, Switzerland), 15(7), 4679-4694 (2010-07-27)
The preparation of carbon nanotube (CNT)/PdO nanoparticles and graphene oxide (GO)/PdO nanoparticle hybrids via a general aqueous solution strategy is reported. The PdO nanoparticles are generated in situ on the CNTs and GO by a one-step "green" synthetic approach in
Zhongbiao Wu et al.
Journal of hazardous materials, 164(2-3), 542-548 (2008-10-01)
Pd-modified TiO(2) prepared by thermal impregnation method was used in this study for photocatalytic oxidation of NO in gas phase. The physico-chemical properties of Pd/TiO(2) catalysts were characterized by X-ray diffraction analysis (XRD), Brunauer-Emmett-Teller measurements (BET), X-ray photoelectron spectrum analysis

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