Quality Level
assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
bp
58 °C/12 mmHg (lit.)
density
0.824 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CP(C(C)(C)C)C(C)(C)C
InChI
1S/C9H21P/c1-8(2,3)10(7)9(4,5)6/h1-7H3
InChI key
JURBTQKVGNFPRJ-UHFFFAOYSA-N
Application
Di-tert-butylmethylphosphine (PtBu2Me) when added as HBF4 salt, enhances the reactivity of palladium-catalyzed direct arylation of heterocylic arenes with aryl chlorides, bromides and azine N-oxides with aryl triflates to form the corresponding biaryl and 2-aryl azine N-oxides, respectively. It may be used in the preparation of CoCl2(PtBu2Me)2, a cobalt phosphine complex, which in combination with methylaluminoxane (MAO) catalyzes the butadiene polymerization to form predominantly the cis-1,4 polymer.
在交叉偶联催化反应中与多种钯复合物一起使用的大体积膦。
signalword
Danger
hcodes
Hazard Classifications
Pyr. Liq. 1 - Skin Corr. 1B
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis, structure, and butadiene polymerization behavior of alkylphosphine cobalt (II) complexes.
Ricci G, et al.
J. Mol. Catal. A: Chem., 226(2), 235-241 (2005)
Jae-Young Lee et al.
Journal of the American Chemical Society, 125(19), 5616-5617 (2003-05-08)
The first method for achieving Hiyama couplings of unactivated alkyl bromides and iodides is reported. The desired carbon-carbon bond formation proceeds under mild conditions (room temperature) with good functional-group tolerance.
Direct arylation of azine N-oxides with aryl triflates.
Schipper DJ, et al.
Tetrahedron, 65(26), 4977-4983 (2009)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 642629-5G | 04061838120434 |