665533
反式-2-(3-氯苯基)乙烯基硼酸频哪醇酯
97%
别名:
2-(E-2-(3-氯苯基)乙烯基)-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷
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关于此项目
经验公式（希尔记法）:
C14H18BClO2
化学文摘社编号:
分子量:
264.56
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C14H18BClO2/c1-13(2)14(3,4)18-15(17-13)9-8-11-6-5-7-12(16)10-11/h5-10H,1-4H3/b9-8+
SMILES string
CC1(C)OB(OC1(C)C)\C=C\c2cccc(Cl)c2
InChI key
NZBKTAJNGYXYSQ-CMDGGOBGSA-N
assay
97%
refractive index
n20/D 1.536
bp
138-140 °C/0.9-1.0 mmHg
density
1.049 g/mL at 25 °C
Application
trans-2-(3-Chlorophenyl)vinylboronic acid pinacol ester can be used as a reactant:
- To prepare aryl derivatives by C−C bond formation via palladium-catalyzed Suzuki−Miyaura reaction.
- In the diastereoselective synthesis of alkenes via K3PO4-promoted transition metal-free nucleophilic substitution of unactivated alkyl triflates.
- To synthesize (3-chlorophenyl)cyclopropyl boronic acid pinacol ester by reacting with diazomethane.
存储类别
12 - Non Combustible Liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
Mild Base Promoted Nucleophilic Substitution of Unactivated sp3-Carbon Electrophiles with Alkenylboronic Acids
Liu Shiwen, et al.
Advanced Synthesis & Catalysis, 360(19), 3667-3671 (2018)
Automated library synthesis of cyclopropyl boronic esters employing diazomethane in a tube-in-tube flow reactor
Koolman HF, et al.
Organic & Biomolecular Chemistry, 14(27), 6591-6595 (2016)
Mild Base Promoted Nucleophilic Substitution of Unactivated sp3-Carbon Electrophiles with Alkenylboronic Acids
Liu Shiwen, et al.
advanced synthesis and catalysis, 360(19), 3667-3671 (2018)
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