666246
1-(2-甲氧基乙氧基)-1-乙烯基环丙烷
别名:
1-乙烯基-1-(2-甲氧基乙氧基)环丙烷
折射率
n20/D 1.441
密度
0.922 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
COCCOC1(CC1)C=C
InChI
1S/C8H14O2/c1-3-8(4-5-8)10-7-6-9-2/h3H,1,4-7H2,2H3
InChI key
YIUPAIQJWAOJKD-UHFFFAOYSA-N
应用
一种有用的支架，用于制备 7 元环体系和双环体系。
能够参与多种铑催化的环加成反应。
Reactant for:
- Rhodium-catalyzed [5+2] cycloaddition with alkynes and allenes
- Cycloaddition/Nazarov cyclization sequence reactions
- Preparation of cyclohexenones by cocyclization with carbon monoxide catalyzed by octacarbonyldicobalt
- Preparation of cyclopentenes by nickel-catalyzed isomerization
警示用语：
Warning
危险声明
预防措施声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
114.8 °F
闪点(°C)
46 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Wender et al.
Organic letters, 2(11), 1609-1611 (2000-06-07)
Described herein is an efficient preparative scale synthesis of 1-(2-methyoxyethoxy)-1-vinylcyclopropane and the investigation of the utility of this reagent as a new five-carbon component in metal-catalyzed [5 + 2] cycloadditions. A new cycloaddition procedure is also described that proceeds up
Zhi-Xiang Yu et al.
Journal of the American Chemical Society, 126(30), 9154-9155 (2004-07-30)
DFT calculations have been applied to investigate the reaction mechanism of rhodium dimer, [Rh(CO)2Cl]2, catalyzed intermolecular (5 + 2) reactions between vinylcyclopropanes and alkynes. The catalytic species is Rh(CO)Cl and the catalytic cycle is through the sequential reactions of cyclopropyl
Hermann A Wegner et al.
Journal of the American Chemical Society, 127(18), 6530-6531 (2005-05-05)
Initial examples of the intermolecular Rh(I)-catalyzed [5+2] cycloaddition reaction of bifunctional allenes and vinylcyclopropanes are described. The reactions proceed with facility and in yields of up to 99% with a variety of alkyne-, ester-, styrene-, or cyano-substituents on the allene
Paul A Wender et al.
Journal of the American Chemical Society, 124(12), 2876-2877 (2002-03-21)
Prompted by our studies of transition metal-catalyzed [4+4], [4+2], [5+2], and [6+2] cycloadditions and by the view that these two-component reactions could be intercepted by a third component of one or more atoms, a new three-component transition metal-catalyzed cycloaddition is
Paul A Wender et al.
Journal of the American Chemical Society, 127(9), 2836-2837 (2005-03-03)
Prompted by the view that intermediates of transition metal-catalyzed reactions could be intercepted by one or more additional components, studies in our laboratory have led to the design and development of new three-component [5+2+1], [4+2+1], and [2+2+1] cycloadditions. These continuing
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