671576
N-苯基羟胺
≥95.0%
别名:
N -羟基苯胺, N-羟基苯胺
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
C6H7NO
化学文摘社编号:
分子量:
109.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-875-6
MDL number:
Assay:
≥95.0%
Form:
solid
产品名称
N-苯基羟胺, ≥95.0%
InChI key
CKRZKMFTZCFYGB-UHFFFAOYSA-N
InChI
1S/C6H7NO/c8-7-6-4-2-1-3-5-6/h1-5,7-8H
SMILES string
ONc1ccccc1
assay
≥95.0%
form
solid
mp
80-84 °C
storage temp.
−20°C
Quality Level
Application
N-苯基羟胺作为起始材料，可用于下列合成反应：
- 通过连续3,3-重排和环脱水反应，用金催化剂与脂肪族末端炔烃进行处理，合成2-烷基吲哚。
- 通过三组分一锅催化法，与醛和 α, β不饱和醛合成异恶唑烷。
- 通过homo3+2偶极环加成反应，处理醛和环丙烷，合成四氢1,2-恶嗪。
signalword
Danger
hcodes
pcodes
Hazard Classifications
Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Copper-catalyzed amination of alkenes and ketones by phenylhydroxylamine.
Ho C-M and Lau T-C
New. J. Chem., 24(11), 859-863 (2000)
Au-catalyzed synthesis of 2-alkylindoles from N-arylhydroxylamines and terminal alkynes
Wang Y, et al.
Chemical Communications (Cambridge, England), 47(27), 7815-7817 (2011)
Nilanjana Chowdhury et al.
Bioorganic & medicinal chemistry letters, 20(18), 5414-5417 (2010-08-21)
Photoinduced homolytic fission of nitrogen-oxygen bond in N,O-diacyl-4-benzoyl-N-phenylhydroxylamines using 310 nm UV light for 10 min produced acylaminyl and acyloxy radicals, which resulted in single strand cleavage of DNA at pH 7.0. Further the DNA cleaving ability of N,O-diacyl-4-benzoyl-N-phenylhydroxylamines found
T P Bradshaw et al.
Free radical biology & medicine, 18(2), 279-285 (1995-02-01)
Previous studies have shown that incubation of rat red blood cells in vitro with phenylhydroxylamine (50-300 microM) induces rapid splenic sequestration of the red cells on reintroduction to isologous rats. EPR and the spin trapping agent, 5,5-dimethyl-1-pyrroline-N-oxide (DMPO), were utilized
M M Shah et al.
Biochemical and biophysical research communications, 241(3), 794-796 (1998-01-22)
Nitrobenzene was reduced in a solution containing ferredoxin NADP oxidoreductase (FNR) from spinach leaves and NADPH generating system. The product of nitrobenzene was identified as phenylhydroxylamine (PHA) on 1:1 basis.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持