方案
≥95.0%
表单
solid
mp
80-84 °C
储存温度
−20°C
SMILES字符串
ONc1ccccc1
InChI
1S/C6H7NO/c8-7-6-4-2-1-3-5-6/h1-5,7-8H
InChI key
CKRZKMFTZCFYGB-UHFFFAOYSA-N
应用
N-苯基羟胺作为起始材料，可用于下列合成反应：
- 通过连续3,3-重排和环脱水反应，用金催化剂与脂肪族末端炔烃进行处理，合成2-烷基吲哚。
- 通过三组分一锅催化法，与醛和 α, β不饱和醛合成异恶唑烷。
- 通过homo3+2偶极环加成反应，处理醛和环丙烷，合成四氢1,2-恶嗪。
警示用语：
Danger
危险声明
预防措施声明
危险分类
Acute Tox. 3 Oral
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Z He et al.
European journal of biochemistry, 267(4), 1110-1116 (2000-02-15)
Hydroxylaminobenzene mutase is the enzyme that converts intermediates formed during initial steps in the degradation of nitrobenzene to a novel ring-fission lower pathway in Pseudomonas pseudoalcaligenes JS45. The mutase catalyzes a rearrangement of hydroxylaminobenzene to 2-aminophenol. The mechanism of the
Magnesium iodide promoted reactions of nitrones with cyclopropanes: a synthesis of tetrahydro-1, 2-oxazines.
Ganton M D and Kerr M A
The Journal of Organic Chemistry, 69(24), 8554-8557 (2004)
Diastereoselective synthesis of pyrrolidines using a nitrone/cyclopropane cycloaddition: synthesis of the tetracyclic core of nakadomarin A.
Young L S, et al.
Organic Letters, 7(5), 953-955 (2005)
Three-component homo 3+ 2 dipolar cycloaddition. A diversity-oriented synthesis of tetrahydro-1, 2-oxazines and FR900482 skeletal congeners
Young IS and Kerr MA
Organic Letters, 6(1), 139-141 (2004)
M M Shah et al.
Biochemical and biophysical research communications, 241(3), 794-796 (1998-01-22)
Nitrobenzene was reduced in a solution containing ferredoxin NADP oxidoreductase (FNR) from spinach leaves and NADPH generating system. The product of nitrobenzene was identified as phenylhydroxylamine (PHA) on 1:1 basis.
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