Name: (<I>R</I>)-VANOL
Brand: ALDRICH

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经验公式（希尔记法）:

C₃₂H₂₂O₂

CAS Number:

分子量:

438.52

MDL编号:

UNSPSC代码:

12352005

PubChem化学物质编号:

NACRES:

NA.22

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97%

solid

[α]20/D +310°, c = 1 in chloroform

200-204 °C

phenyl

Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6

1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H

NDTDVKKGYBULHF-UHFFFAOYSA-N

已证实 VANOL 是用于催化型不对称 Diels-Alder 反应、亚胺羟醛反应以及氮杂环丙化反应的绝佳配体。

(R)-VANOL is a vaulted biaryl ligand that may be used in the following processes:

Transformation of 3-substituted cyclobutanones to enantiopure γ-butyrolactones via asymmetric Baeyer-Villiger Reaction in the presence of an aluminum catalyst.
Asymmetric aziridination of N-(4-(Methylsulfonyl)benzylidene)diphenylmethanamine to form (2S,3S)-ethyl 1-benzhydryl-3-(4-(methylsulfonyl)phenyl) aziridine-2-carboxylate.
Conjugate addition of terminal alkynes to 2-arylidene-1,3-diketones with high enantioselectivity in the presence of diethyl zinc.