679712
S-甲基 N-(2,2,2-三氯乙氧磺酰基)碳氯亚胺硫代酸酯
97%
别名:
N-(2,2,2-三氯乙氧磺酰基)碳氯硫代酸 S-甲酯
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关于此项目
经验公式（希尔记法）:
C4H5Cl4NO3S2
化学文摘社编号:
分子量:
321.03
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
表单
solid
mp
75-79 °C
官能团
chloro
thioether
SMILES字符串
CS\C(Cl)=N\S(=O)(=O)OCC(Cl)(Cl)Cl
InChI
1S/C4H5Cl4NO3S2/c1-13-3(5)9-14(10,11)12-2-4(6,7)8/h2H2,1H3/b9-3+
InChI key
NGCLYHLLOXVGSU-YCRREMRBSA-N
应用
制备受保护的胍衍生物的试剂。
Reactant for preparation of:
- Muramycin analogs as antibacterial agents against drug-resistant bacteria
- L-epicapreomycidine using rhodium-catalyzed stereoselective oxidative cyclization
- (+)-gonyautoxin 3 via Rh-catalyzed amination
- (+)-monobromophakellin and (+)-phakellin via a strategy applicable to synthesis of more complex members of this family of marine sponge-derived alkaloids including palau′amine
- 2-imidazolidinones and 2-imino-1,3-imidazolidines
Mihyong Kim et al.
Organic letters, 8(6), 1073-1076 (2006-03-10)
[reaction: see text] Oxidative C-H amination of N-trichloroethoxysulfonyl-protected ureas and guanidines is demonstrated to proceed in high yield for tertiary and benzylic-derived substrates. The success of these reactions is predicated on the choice of the electron-withdrawn 2,2,2-trichloroethoxysulfonyl (Tces) protecting group
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