685011
（1,5-环辛二烯）-η5-茚基）铱（I）
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关于此项目
线性分子式:
(C9H7)Ir(C8H12)
化学文摘社编号:
分子量:
414.54
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
表单
solid
反应适用性
core: iridium
reagent type: catalyst
mp
126-131 °C
SMILES字符串
[Ir].C1CC=CCCC=C1.[CH]2[CH][C]3C=CC=C[C]3[CH]2
InChI
1S/C9H7.C8H12.Ir/c1-2-5-9-7-3-6-8(9)4-1;1-2-4-6-8-7-5-3-1;/h1-7H;1-2,7-8H,3-6H2;/b;2-1-,8-7-;
InChI key
YLWHBOFZCLHZHQ-GHDUESPLSA-N
应用
C-H 活化/硼化用催化剂
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Jian-Yang Cho et al.
Science (New York, N.Y.), 295(5553), 305-308 (2001-11-24)
Arylboron compounds have intriguing properties and are important building blocks for chemical synthesis. A family of Ir catalysts now enables the direct synthesis of arylboron compounds from aromatic hydrocarbons and boranes under "solventless" conditions. The Ir catalysts are highly selective
Robert E Maleczka et al.
Journal of the American Chemical Society, 125(26), 7792-7793 (2003-06-26)
An efficient one-pot C-H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bearing ortho-/para-directing groups, as such substrates are difficult to access by other phenol syntheses.
商品
Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.
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