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Merck
CN

703214

二-四丁铵顺式-双(异硫氰基)双(2,2′-联吡啶-4,4′-二羧基)钌(II)

95% (NMR)

别名:

Greatcell Solar®, N-719 染料

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关于此项目

经验公式(希尔记法):
C58H86N8O8RuS2
化学文摘社编号:
分子量:
1188.55
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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产品名称

二-四丁铵顺式-双(异硫氰基)双(2,2′-联吡啶-4,4′-二羧基)钌(II), 95% (NMR)

InChI

1S/2C16H36N.2C12H8N2O4.2CNS.Ru/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*5-16H2,1-4H3;2*1-6H,(H,15,16)(H,17,18);;;/q2*+1;;;2*-1;+2/p-2

SMILES string

S=C=N[Ru]N=C=S.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.OC(=O)c1ccnc(c1)-c2cc(ccn2)C([O-])=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C([O-])=O

InChI key

MQGCPZMVNHGIPF-UHFFFAOYSA-L

assay

95% (NMR)

form

powder

composition

Dye content, ≥90% HPLC

mp

250-260 °C

λmax

534, 393, 313 nm (lit.)

Quality Level

Application

N-719染料广泛用作敏化剂,可通过刮刀技术将其涂覆在氧化铟锡(ITO)基底上,结合不同的光阳极材料,如结合氧化钛(TiO2)、 氧化锌(ZnO) 与金纳米颗粒(nanourchin) 一起应用于染料敏化太阳能电池(DSSC)。

General description

二-四丁基铵顺式-双(异硫氰酸)双(2,2′-联吡啶-4,4′-二羧酸)钌(II)(N-719染料)是钌聚吡啶基混合物,用作光敏剂。 它充当介质,在电解太阳能电池内有效吸收光子和转移电子。

Legal Information

Greatcell Solar Materials Pty Ltd的产品。
Greatcell Solar是Greatcell Solar Materials Pty Ltd的注册商标。
Greatcell Solar is a registered trademark of Greatcell Solar

pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Resp. Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What are the advantages of dye solar cells?

    Dye solar cells (DSCs) are 3rd generation solar cells with the promise of high efficiency combined with low production costs.

  6. What can cause degradation of the dye solar cell?

    Dye solar cells degrade from ultraviolet radiation.  For this reason, the barrier may include UV stabilizers and/or UV absorbing luminescent chromophores (which emit at longer wavelengths) and antioxidants to protect and improve the efficiency of the cell.

  7. What are the disadvantages of dye solar cells?

    The major disadvantage to the dye solar cell design is the use of a liquid electrolyte, which has temperature stability issues. The electrolyte can freeze at low temperatures and expand at higher temperatures.  It the electrolytes freezes, power production would cease, and it could potentially lead to physical damage.  If the liquid expands at higher temperatures, sealing the panels would be difficult.

  8. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

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Journal of Semiconductors, 39(3), 033005-033005 (2018)
Nanoforest of hydrothermally grown hierarchical ZnO nanowires for a high efficiency dye-sensitized solar cell
Ko SH, et al.
Nano Letters, 11(2), 666-671 (2011)
Au nanoparticle-decorated urchin-like TiO2 hierarchical microspheres for high performance dye-sensitized solar cells
Li Y, et al.
Electrochimica Acta, 293(2), 230-239 (2019)
Enhancing near-infrared solar cell response using upconverting transparentceramics
Liu M, et al.
Solar Energy Materials and Solar Cells, 95(2), 800-803 (2011)
Ruthenium sensitizers and their applications in dye-sensitized solar cells
Hara K and Koumura N
International Journal of Photoenergy (2012)

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While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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