705098
(S,S)-2-烯丙基-1,3-双(4-溴苯甲基)-2-氯八氢-2-1H-1,3,2-苯并二氮杂硅杂环戊二烯
95%
别名:
(S,S)-1,3-双[(4-溴苯基)甲基]-2-氯八氢-2-(2-丙烯基)-1H-1,3,2-苯并二氮杂硅杂环戊二烯
方案
95%
表单
solid
旋光性
[α]22/D +54°, c = 1 in chloroform
mp
94-99 °C
储存温度
2-8°C
SMILES字符串
Cl[Si]1(CC=C)N(Cc2ccc(Br)cc2)[C@H]3CCCC[C@@H]3N1Cc4ccc(Br)cc4
InChI
1S/C23H27Br2ClN2Si/c1-2-15-29(26)27(16-18-7-11-20(24)12-8-18)22-5-3-4-6-23(22)28(29)17-19-9-13-21(25)14-10-19/h2,7-14,22-23H,1,3-6,15-17H2/t22-,23-/m0/s1
InChI key
JTYONYYNZDUUGN-GOTSBHOMSA-N
应用
An operationally simple regioselective and enantioselective allylation of beta-diketones to provide tertiary carbinols
法律信息
美国专利 No.7,534,905
Wesley A Chalifoux et al.
Nature, 487(7405), 86-89 (2012-07-06)
The enantioselective allylation of ketones is a problem of fundamental importance in asymmetric reaction design, especially given that only a very small number of methods can generate tertiary carbinols. Despite the vast amount of attention that synthetic chemists have given
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