710075
(Thiomorpholinium-4-ylmethyl)trifluoroborate
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关于此项目
经验公式（希尔记法）:
C5H11BF3NS
化学文摘社编号:
分子量:
185.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Form:
solid
InChI
1S/C5H10BF3NS/c7-6(8,9)5-10-1-3-11-4-2-10/h1-5H2/q-1/p+1
SMILES string
F[B-](F)(F)C[NH+]1CCSCC1
InChI key
VUNVVPNMYVRSKZ-UHFFFAOYSA-O
description
internal salt
form
solid
mp
146-156 °C
Application
Organotrifluoroborate involved in Suzuki-Miyaura cross-coupling reactions and cross coupling with mesylated phenol derivatives
Organotrifluoroborates as versatile and stable boronic acid surrogates
Organotrifluoroborates as versatile and stable boronic acid surrogates
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Gary A Molander et al.
Organic letters, 13(5), 1242-1245 (2011-02-08)
A large array of aryl and heteroaryl mesylates have been successfully employed as electrophiles in a Csp(2)-Csp(3) Suzuki-Miyaura cross-coupling with potassium ammonio- and amidomethyltrifluoroborates to afford the corresponding products in high yields.
Jessica Raushel et al.
The Journal of organic chemistry, 76(8), 2762-2769 (2011-03-17)
A reinvestigation into the chemical composition of potassium aminomethyltrifluoroborates is reported. These trifluoroborato salts have been reassigned as zwitterionic ammoniomethyltrifluoroborates. Minor adjustments to the previously disclosed reaction conditions are reported that permit a similar level of activity as nucleophiles in
商品
Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.
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