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Merck
CN

714860

Sigma-Aldrich

1,8-二氮杂双环[5.4.0]十一碳-7-烯 溶液

1 M in ethyl acetate

别名:

DBU 溶液

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关于此项目

经验公式(希尔记法):
C9H16N2
分子量:
152.24
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
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浓度

1 M in ethyl acetate

折射率

n20/D 1.395

密度

0.908 g/mL at 25 °C

SMILES字符串

C1CCN2CCCN=C2CC1

InChI

1S/C9H16N2/c1-2-5-9-10-6-4-8-11(9)7-3-1/h1-8H2

InChI key

GQHTUMJGOHRCHB-UHFFFAOYSA-N

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Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

26.6 °F - closed cup

闪点(°C)

-3.0 °C - closed cup

法规信息

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Gui-Ling Zhao et al.
Organic letters, 7(20), 4527-4530 (2005-09-24)
[reaction: see text] DBU-catalyzed reactions of salicylic aldehydes with 3-methylpenta-3,4-dien-2-one, 3-benzylpenta-3,4-dien-2-one, or ethyl 2-methylbuta-2,3-dienoate gave the corresponding functionalized 2H-1-chromenes in good to excellent yields and good diastereoselectivities in some cases in DMSO, respectively.
Ning Zhu et al.
Journal of combinatorial chemistry, 12(4), 531-540 (2010-06-01)
The thiol-disulfide dynamic interchange reaction mediated by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) was extensively studied. By this synthetic method sulfides can be prepared successfully within seconds in high yields at room temperature from stable and readily available disulfides and an alkylating agent. The
Matthew O'Reilly et al.
Dalton transactions (Cambridge, England : 2003), (31)(31), 6092-6095 (2010-05-08)
With the new chiral phosphine ligand DBUP, obtained from DBU and Ph(2)PCl, a remarkable anion effect was observed on the diastereoselective formation of the bischelated complexes [Ni(DBUP)(2)](X)(n) (X = Cl, Br, n = 2; X = NiCl(4), n = 1)
Naoto Utsumi et al.
Organic letters, 10(16), 3405-3408 (2008-07-18)
Direct organocatalytic Mannich-type reactions of thioesters provide for the expedient and diastereoselective synthesis of protected beta-amino acids. A variety of thioesters were found to be reactive with different imines under mild conditions to provide beta-amino acids in good yields. This
Wim L Noorduin et al.
Angewandte Chemie (International ed. in English), 48(51), 9600-9606 (2009-12-01)
A century ago Wilhelm Ostwald received the Nobel Prize for Chemistry. Although Ostwald was never significantly involved with the phenomenon of chirality, one of his discoveries, Ostwald ripening, is thought to be involved in a recently discovered method in which

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