72453
四丁基硫酸氢铵 溶液
~55% in H2O, liquid
别名:
四丁基酒石酸氢铵 溶液
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(HSO4)
CAS Number:
分子量:
339.53
Beilstein:
3599663
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.22
Product Name
四丁基硫酸氢铵 溶液, ~55% in H2O
表单
liquid
质量水平
浓度
~55% in H2O
SMILES字符串
OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1
InChI key
SHFJWMWCIHQNCP-UHFFFAOYSA-M
应用
四丁基硫酸氢铵（Bu4NHSO4）可与二水氟化钾一同使用，通过氮杂环丙烷的开环反应而用于合成β-氟胺衍生物。它还可用作催化剂，分别将氮丙啶和环氧化物水解成相应的β-氨基醇和1,2-二醇。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Ren-Hua Fan et al.
The Journal of organic chemistry, 69(2), 335-338 (2004-01-17)
Potassium fluoride combined with tetrabutylammonium bisulfate is an efficient reagent to convert a variety of aziridines derived from cyclic and acyclic alkenes to beta-fluoro amine derivatives in high yield.
Tetrabutylammonium bisulfate: a new effective catalyst for the hydrolysis of aziridines or epoxides.
Ren-Hua Fan et al.
Organic & biomolecular chemistry, 1(9), 1565-1567 (2003-08-21)
Bu4NHSO4 (TBAHS) is an effective catalyst for the hydrolysis of aziridines and epoxides under mild and non-metal conditions to give the corresponding beta-amino alcohols and 1,2-diols in high yields. The catalyst can be recycled.
K M Frankowski et al.
Journal of dairy science, 97(9), 5356-5370 (2014-07-16)
Many food companies are trying to limit the amount of sodium in their products. Permeate, the liquid remaining after whey or milk is ultrafiltered, has been suggested as a salt substitute. The objective of this study was to determine the
Erbo Shi et al.
Organic letters, 14(13), 3384-3387 (2012-06-27)
A metal-free C-H oxidation for the construction of allylic esters has been developed. The use of a commercially available and inexpensive catalyst and oxidant, and readily available starting materials, coupled with the operational simplicity of the reaction, renders the methodology
Fabio Galeotti et al.
Journal of chromatography. A, 1284, 141-147 (2013-03-05)
In this study, by using tetrabutylammonium bisulfate as ion-pairing reagent, we were able to separate all the main heparin/heparan sulfate disaccharides generated by the action of heparinases along with the main Hep tetrasaccharide possessing a 3-O-sulfate group on the sulfoglucosamine
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