738484
Potassium 1-Boc-1H-indole-5-trifluoroborate
97%
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关于此项目
经验公式（希尔记法）:
C13H14BF3KNO2
化学文摘社编号:
分子量:
323.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Assay:
97%
Form:
solid
产品名称
Potassium 1-Boc-1H-indole-5-trifluoroborate, 97%
InChI
1S/C13H14BF3NO2.K/c1-13(2,3)20-12(19)18-7-6-9-8-10(14(15,16)17)4-5-11(9)18;/h4-8H,1-3H3;/q-1;+1
SMILES string
[K+].CC(C)(C)OC(=O)n1ccc2cc(ccc12)[B-](F)(F)F
InChI key
WQXAJDXDSOGMRW-UHFFFAOYSA-N
assay
97%
form
solid
mp
190-195 °C
Application
Potassium 1-Boc-1H-indole-5-trifluoroborate can be used as a substrate in:
- The cross-coupling reaction of 2(chloromethyl)-2,1-borazaronaphthalenes with trifluoroborates.
- Fluorination reactions of potassium salts of aryl and heteroaryl trifluoroborates.
- Nitrosation reactions of potassium trifluoroborates using nitrosonium tetrafluoroborate.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Silver-mediated fluorination of potassium aryltrifluoroborates with Selectfluor
Dubbaka SR, et al.
Tetrahedron, 70(51), 9676-9681 (2014)
Accessing 2-(Hetero) arylmethyl-,-allyl-, and-propargyl-2, 1-borazaronaphthalenes: Palladium-Catalyzed Cross-Couplings of 2-(Chloromethyl)-2, 1-borazaronaphthalenes
Molander GA, et al.
Organic Letters, 16(22), 6024-6027 (2014)
Gary A Molander et al.
The Journal of organic chemistry, 77(9), 4402-4413 (2012-04-25)
Organotrifluoroborates have emerged as an alternative to toxic and air- and moisture-sensitive organometallic species for the synthesis of functionalized aryl and heteroaryl compounds. It has been shown that the trifluoroborate moiety can be easily converted into a variety of different
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