743739
2H,6H-[1,2]Iodoxolo[4,5,1-hi][1,2]benziodoxole-2,6-dione
96.0-104.0 wt. % (T)
别名:
2aλ3-Ioda-2,3-dioxa-cyclopenta[cd]indene-1,4-dione, Iodosodilactone
方案
96.0-104.0% (wt., T)
表单
solid
官能团
iodo
SMILES字符串
O=C1O[I]2OC(=O)c3cccc1c23
InChI
1S/C8H3IO4/c10-7-4-2-1-3-5-6(4)9(12-7)13-8(5)11/h1-3H
InChI key
DHIWEENQJCGNME-UHFFFAOYSA-N
应用
2H,6H-[1,2]Iodoxolo[4,5,1-hi][1,2]benziodoxole-2,6-dione is an iodine(III) reagent that can be used:
- As a coupling reagent in many organic reactions like amidation, peptide coupling, and esterification to yield amides, esters, peptides, and macrocyclic lactones without racemization.
- As an oxidant in the arylation reactions of fluorophenols.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
此项目有
Synthesis and properties of two iodosolactones.
Agosta, W. C.
Tetrahedron Letters, 6, 2681-2685 (1965)
Regioselective oxidative arylation of fluorophenols
Yu C and Patureau FW
Angewandte Chemie (International Edition in English), 58(51), 18530-18534 (2019)
Jun Tian et al.
Organic letters, 14(12), 3020-3023 (2012-06-08)
A hypervalent iodine(III) reagent plays a novel role as an efficient coupling reagent to promote the direct condensation between carboxylic acids and alcohols or amines to provide esters, macrocyclic lactones, amides, as well as peptides without racemization. The regeneration of
Recyclable hypervalent iodine (III) reagent iodosodilactone as an efficient coupling reagent for direct esterification, amidation, and peptide coupling
Tian J, et al.
Organic Letters, 14(12), 3020-3023 (2012)
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