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Merck
CN

772402

Sigma-Aldrich

PBDTTT-CF

别名:

Poly[1-(6-{4,8-bis[(2-ethylhexyl)oxy]-6-methylbenzo[1,2-b:4,5-b′]dithiophen-2-yl}-3-fluoro-4-methylthieno[3,4-b]thiophen-2-yl)-1-octanone]

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关于此项目

经验公式(希尔记法):
C40H51FO3S4 ]n
化学文摘社编号:
分子量:
727.09 (as monomer)
UNSPSC代码:
12352103
NACRES:
NA.23
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描述

Band gap: 1.77 eV

表单

powder

分子量

average Mw 53,000-83,000 by GPC

轨道能量

HOMO -5.22 eV 
LUMO -3.45 eV 

半导体性质

P-type (mobility=7×10−4 cm2/V·s)

一般描述

PBDTTT-CF is a low band-gap conducting polymer which contains dialkoxyl benzodithiophene and fluorine substituted thieno[3,4-b]thiophene groups. It can be used as a donor material with a power conversion efficiency of 6.77%.

应用

Low band gap polymer; for high-efficiency organic solar cells (OPVs) application

OPV Device Structure: ITO/PEDOT:PSS/PBDTTT-CF :PC71BM/Ca/Al; achieving power conversion efficiency as high as 6.77%; as certified by the National Renewable Energy Laboratory (NREL).
PBDTTT-CF is mainly used in the fabrication of polymeric solar cells and organic solar cells.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Synthesis and photovoltaic properties of an alternating phenylenevinylene copolymer with substituted-triphenylamine units along the backbone for bulk heterojunction and dye-sensitized solar cells
Mikroyannidis JA, et al.
Journal of Power Sources, 196(4), 2364-2372 (2011)
A polybenzo [1, 2-b: 4, 5-b?] dithiophene derivative with deep HOMO level and its application in high-performance polymer solar cells
Huo L, et al.
Angewandte Chemie (International Edition in English), 122(8), 1542-1545 (2010)
Polymer solar cells with enhanced open-circuit voltage and efficiency
Chen H, et al.
Nature Photonics, 3(11), 649-649 (2009)
Towards organic solar cells without the hole transporting layer on the plasmon-enhanced ITO electrode
Vojtko A, et al.
physica status solidi (a), 212(4), 867-876 (2015)
Polymer solar cells with enhanced open-circuit voltage and efficiency
Nature Photonics, 3, 649-653 (2009)

商品

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

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