质量水平
方案
≥80%
表单
liquid
反应适用性
reagent type: reductant
密度
1.136 g/mL at 25 °C
SMILES字符串
OCCCP(CCCO)CCCO
InChI
1S/C9H21O3P/c10-4-1-7-13(8-2-5-11)9-3-6-12/h10-12H,1-9H2
InChI key
YICAEXQYKBMDNH-UHFFFAOYSA-N
一般描述
三（羟丙基）膦（THPP)是一种还原剂，广泛用于水性–有机介质中小分子二硫键的还原裂解。
应用
三（羟丙基）膦可用于：
- 作为还原剂用于将脱氢抗坏血酸还原成抗坏血酸
- 小分子二硫键的裂解
- 作为多硫化物转化的催化剂。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Suttipong Suttapitugsakul et al.
Molecular bioSystems, 13(12), 2574-2582 (2017-10-12)
Mass spectrometry (MS) has become an increasingly important technique to analyze proteins. In popular bottom-up MS-based proteomics, reduction and alkylation are routine steps to facilitate peptide identification. However, incomplete reactions and side reactions may occur, which compromise the experimental results.
Tris (3-hydroxypropyl) phosphine (THPP): A mild, air-stable reagent for the rapid, reductive cleavage of small-molecule disulfides.
McNulty J, et al.
Bioorganic & Medicinal Chemistry Letters, 25(19), 4114-4117 (2015)
One-Pot Peptide Ligation-Oxidative Cyclization Protocol for the Preparation of Short-/Medium-Size Disulfide Cyclopeptides.
Spengler J, et al.
Organic Letters, 20(14), 4306-4309 (2018)
Designing dendritic polymers containing phosphorus donor ligands and their corresponding transition metal complexes.
Dasgupta M, et al.
Coordination Chemistry Reviews, 233(19), 223-235 (2002)
Kristine Opsvik Wikene et al.
Journal of photochemistry and photobiology. B, Biology, 171, 27-33 (2017-05-05)
Natural deep eutectic solvents (NADES) are a third class of liquids, separate from water and lipids. Some NADES, especially those containing organic acids, have been suggested to possess antimicrobial properties. Such properties may be advantageous when NADES are used as
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