777854
三羟丙基膦
≥80%
别名:
THPP
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关于此项目
经验公式（希尔记法）:
C9H21O3P
化学文摘社编号:
分子量:
208.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352128
MDL number:
Assay:
≥80%
Form:
liquid
InChI
1S/C9H21O3P/c10-4-1-7-13(8-2-5-11)9-3-6-12/h10-12H,1-9H2
SMILES string
OCCCP(CCCO)CCCO
InChI key
YICAEXQYKBMDNH-UHFFFAOYSA-N
assay
≥80%
form
liquid
reaction suitability
reagent type: reductant
density
1.136 g/mL at 25 °C
Quality Level
General description
三（羟丙基）膦（THPP)是一种还原剂，广泛用于水性–有机介质中小分子二硫键的还原裂解。
Application
三（羟丙基）膦可用于：
- 作为还原剂用于将脱氢抗坏血酸还原成抗坏血酸
- 小分子二硫键的裂解
- 作为多硫化物转化的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Tris (3-hydroxypropyl) phosphine (THPP): A mild, air-stable reagent for the rapid, reductive cleavage of small-molecule disulfides.
McNulty J, et al.
Bioorganic & Medicinal Chemistry Letters, 25(19), 4114-4117 (2015)
Suttipong Suttapitugsakul et al.
Molecular bioSystems, 13(12), 2574-2582 (2017-10-12)
Mass spectrometry (MS) has become an increasingly important technique to analyze proteins. In popular bottom-up MS-based proteomics, reduction and alkylation are routine steps to facilitate peptide identification. However, incomplete reactions and side reactions may occur, which compromise the experimental results.
Designing dendritic polymers containing phosphorus donor ligands and their corresponding transition metal complexes.
Dasgupta M, et al.
Coordination Chemistry Reviews, 233(19), 223-235 (2002)
One-Pot Peptide Ligation-Oxidative Cyclization Protocol for the Preparation of Short-/Medium-Size Disulfide Cyclopeptides.
Spengler J, et al.
Organic Letters, 20(14), 4306-4309 (2018)
Kristine Opsvik Wikene et al.
Journal of photochemistry and photobiology. B, Biology, 171, 27-33 (2017-05-05)
Natural deep eutectic solvents (NADES) are a third class of liquids, separate from water and lipids. Some NADES, especially those containing organic acids, have been suggested to possess antimicrobial properties. Such properties may be advantageous when NADES are used as
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