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Merck
CN

900635

Sigma-Aldrich

2-甲基环丙基亚磺酸钠

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关于此项目

经验公式(希尔记法):
C4H7NaO2S
分子量:
142.15
UNSPSC代码:
12352200
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表单

powder or crystals

反应适用性

reaction type: C-C Bond Formation
reaction type: C-H Activation
reagent type: catalyst

应用

The following Baran sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

象形图

Exclamation mark

警示用语:

Warning

危险声明

预防措施声明

危险分类

Eye Irrit. 2

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

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Pd (II)-Catalyzed Direct Sulfonylation of Unactivated C (sp3)?H Bonds with Sodium Sulfinates.
Rao W H, et al.
Organic Letters, 17(14), 3552-3555 (2015)
Palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts.
Reeves D C, et al.
Tetrahedron Letters, 50(24), 2870-2873 (2009)
Copper-Catalyzed Aerobic Decarboxylative Sulfonylation of Cinnamic Acids with Sodium Sulfinates: Stereospecific Synthesis of (E)-Alkenyl Sulfones.
Jiang Q, et al.
The Journal of Organic Chemistry, 79(16), 7372-7379 (2014)
Cu-Catalyzed Deoxygenative C2-Sulfonylation Reaction of Quinoline N-Oxides with Sodium Sulfinate.
Du B, et al.
Organic Letters, 18(16), 4144-4147 (2016)

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