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Merck
CN

930946

硝酸锂

greener alternative

≥99.9% trace metals basis

别名:

Lithium salt of nitric acid

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关于此项目

线性分子式:
LiNO3
化学文摘社编号:
分子量:
68.95
UNSPSC Code:
12352302
NACRES:
NA.21
MDL number:
Assay:
≥99.9% trace metals basis
Grade:
anhydrous
battery grade
Form:
powder
Solubility:
H2O: soluble (highly soluble(lit.))
acetone: soluble ((lit.))
alcohols: soluble ((lit.))
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产品名称

硝酸锂, ≥99.9% trace metals basis

InChI

1S/Li.NO3/c;2-1(3)4/q+1;-1

SMILES string

[Li+].[O-][N+]([O-])=O

InChI key

IIPYXGDZVMZOAP-UHFFFAOYSA-N

grade

anhydrous
battery grade

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

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impurities

≤0.5 wt. % H2O
≤1000 ppm (trace metals analysis)

mp

264 °C (lit.)

solubility

H2O: soluble (highly soluble(lit.))
acetone: soluble ((lit.))
alcohols: soluble ((lit.))

anion traces

chloride (Cl-): ≤500 ppm
sulfate (SO42-): ≤200 ppm

application(s)

battery precursors
catalysts
material synthesis precursor

greener alternative category

Quality Level

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Application

Researchers and manufacturers use lithium nitrate in the preparation of many lithium compounds, most notably lithium nickel oxide (LiNiO2) and lithium manganese oxide (LiMn2O4). One common strategy for synthesizing these lithium metal oxides involves a high-temperature reaction of lithium nitrate with a metal carbonate, like nickel carbonate, or with a metal oxide, like manganese oxide. At temperatures above 650 °C, lithium nitrate evolves oxygen gas and nitrogen dioxide gas and decomposes through a complex process into lithium oxide, which reacts with the metal precursors to form the tertiary or quaternary lithium metal oxides. Researchers have used this technique to prepare exciting new materials, like LiAl0.25Ni0.75O2 as a cathode material in lithium-ion batteries and LiGa5O8 as a phosphor for optical information storage.
Because lithium nitrate is soluble in water, researchers also use lithium nitrate in the synthesis of lithium compounds using a host of solution-based chemistries. For example, microwave-induced combustion using solutions of lithium nitrate has yielded olivine-type lithium iron phosphate (LiFePO4), lithium cobalt oxide (LiCoO2), and lithium titanium oxides (ex. Li4Ti5O12 and Li2TiO3). Hydrothermal processing, sol-gel processing, spray pyrolysis, co-precipitation pre-processing, and Li emulsion-drying methods have all used lithium nitrate as a reactant to form lithium metal oxides. These techniques can yield controlled particle size, grain size, crystallinity, or facilitate the introduction of dopants for engineering the properties of the products, often explored for next-generation lithium-ion batteries.
Our battery grade lithium nitrate with ≥99.9% trace metals purity and low chloride and sulfate impurities, is designed as a precursor for cathode materials for lithium-ion batteries.

General description

Anhydrous lithium nitrate is a white, crystalline salt. The anhydrous form is hygroscopic and deliquescent. The salt is soluble in water, ethanol, methanol, pyridine, ammonia, and acetone. Like some other metal nitrates, lithium nitrate has a low melting point of only 264 °C, and decomposes above 600 °C. Because of its low melting point, it is used to produce low-melting fused-salt mixtures in ceramics and heat-exchange media.
Lithium nitrate is produced by the acid-base reaction between nitric acid and lithium carbonate, which evolves carbon dioxide and water. The resulting material is dried, purified, and heated to form the anhydrous product.
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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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A review of recent developments in the synthesis procedures of lithium iron phosphate powders.
Jugovic D, et al.
Journal of Power Sources, 190, 538-544 (2009)
Electrochemistry and Structural Chemistry of LiNiO2 (R3m) for 4 Volt Secondary Lithium Cells
Ohzuku T, et al.
Journal of the Electrochemical Society, 140, 1862-1862 (1993)
Synthesis and Characterization of LiAI1/4Ni3/4O2 (R3m) for Lithium-Ion (Shuttlecock) Batteries.
Ohzuku T, et al.
Journal of the Electrochemical Society, 142, 4033-4033 (1995)
Synthesis Conditions and Oxygen Stoichiometry Effects on Li Insertion into the Spinel LiMn2O4
Tarascon J M, et al.
Journal of the Electrochemical Society, 141, 1421-1421 (1994)
Feng Liu et al.
Scientific reports, 3, 1554-1554 (2013-03-28)
In conventional photostimulable storage phosphors, the optical information written by x-ray or ultraviolet irradiation is usually read out as a visible photostimulated luminescence (PSL) signal under the stimulation of a low-energy light with appropriate wavelength. Unlike the transient PSL, here

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