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Merck
CN

931578

氯化钌 (III) 水合物

≥99.9% trace metals basis

别名:

三氯化钌

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关于此项目

线性分子式:
RuCl3 · xH2O
化学文摘社编号:
分子量:
207.43 (anhydrous basis)
UNSPSC Code:
12352302
NACRES:
NA.21
MDL number:
Assay:
≥99.9% trace metals basis
Form:
powder
Solubility:
acetone: soluble ((lit.))
ethanol: soluble
water: soluble
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产品名称

氯化钌 (III) 水合物, ≥99.9% trace metals basis

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

SMILES string

O.Cl[Ru](Cl)Cl

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: ruthenium

impurities

≤1000.0 ppm (trace metals analysis)

solubility

acetone: soluble ((lit.))
ethanol: soluble
water: soluble

density

3.11 g/cm3

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

Quality Level

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Application

Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. Our RuCl3·H2O with 99.9% trace metals purity is well-suited for applications in materials science. One common application of ruthenium trichloride hydrate is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions. Researchers have used our ruthenium chloride hydrate to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles.
Another common application of ruthenium chloride hydrate is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride hydrate for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
For use in all these applications, also consider our higher-purity ruthenium chloride hydrate, 463779, with trace metals purity greater than 99.98%, which offers the best reproducibility and purity.

General description

Ruthenium chloride hydrate is a dark brown or black solid often used as a powder. The hydrate is hygroscopic and is soluble in water, ethanol, acetone, and a wide range of polar organic solvents. The anhydrous form is insoluble.
Industrially, ruthenium trichloride hydrate is produced by dissolving ruthenium oxides in hydrochloric acid. The hydrated salt is obtained by recrystallization.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
Lee, Y., Suntivich, J., et al.
The Journal of Physical Chemistry Letters, 3, 399?404-399?404 (2012)
Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution
Ramalingam, V., et al.
Advanced Materials, 31, e1903841-e1903841 (2019)
Thermally Reduced Ruthenium Nanoparticles as a Highly Active Heterogeneous Catalyst for Hydrogenation of Monoaromatics
Su, F., Lv, L., et al.
Journal of the American Chemical Society, 129, 14213?14223-14213?14223 (2007)
High Performance PtRuIr Catalysts Supported on Carbon Nanotubes for the Anodic Oxidation of Methanol
Liao, S., Holmes, K.A., et al.
Journal of the American Chemical Society, 128, 3504-3505 (2006)
Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction
Scofield, M.E., et al.
Energy & Environmental Science, 8, 350-350 (2015)

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