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Merck
CN

940321

Sigma-Aldrich

硫化锂

99.995% trace metals basis (basis), low sodium, battery grade

别名:

Dilithium monosulfide, Dilithium sulfide

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关于此项目

经验公式(希尔记法):
Li2S
CAS Number:
分子量:
45.95
MDL编号:
UNSPSC代码:
12352300
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等级

battery grade

质量水平

描述

application(s): battery manufacturing

方案

99.995% trace metals basis (basis)

表单

powder

分子量

45.95

组成

Li2S

粒径

100 mesh

沸点

1,372 °C ((lit.))

mp

900-975 °C

溶解性

soluble (reacts with water)

密度

1.66 g/mL at 25 °C (lit.)

痕量阳离子

Na: <35 ppm

储存温度

2-8°C

SMILES字符串

[Li]S[Li]

InChI

1S/2Li.S

InChI key

ZWDBUTFCWLVLCQ-UHFFFAOYSA-N

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一般描述

Lithium sulfide (Li₂S) is a high-purity, inorganic compound that appears as a white to yellowish crystalline powder. It has a molecular weight of 45.95 g/mol and a density of 1.66 g/cm³. Lithium sulfide is known for its strong nucleophilic properties and its ability to react readily with water to produce lithium hydroxide and hydrogen sulfide gas. It is also soluble in certain organic solvents, such as pyridine and dimethyl sulfoxide. Lithium sulfide crystallizes in an antifluorite structure and melts in the temperature range of 900-975°C. Our high-purity material (99.995% trace metals) is specifically formulated for low sodium content, with less than 35 ppm of sodium metal. Additionally, the material is passed through a 100 mesh sieve, ensuring that most particles are less than 150 microns in size.

应用

High-purity lithium sulfide is primarily used as a precursor in the synthesis of other lithium compounds. In chemical manufacturing, it acts as a precursor for lithium hydride, lithium borohydride, lithium amide, lithium thioacetate, lithium tetrafluoroborate, and others. In the battery industry, our battery grade lithium sulfide is used as a precursor to synthesize sulfide-based solid electrolytes like Li₃PS₄ ([https://www.sigmaaldrich.com/US/en/product/aldrich/916374]), Li₆PS₅Cl ([https://www.sigmaaldrich.com/US/en/product/aldrich/916137]), and Li₁₀SnP₂S₁₂ ([https://www.sigmaaldrich.com/US/en/product/aldrich/915114]). Lithium sulfide also serves as a cathode material in lithium-sulfur batteries, offering a theoretical capacity of up to 1166 mAh/g, nearly four times that of lithium cobalt oxide. This makes it an attractive candidate for next-generation battery technologies. Additionally, lithium sulfide is valuable in the semiconductor industry for the production of thin-film transistors (TFTs) and other electronic devices, particularly lithium sulfide-phosphorus oxide (Li₂S-P₂O₅) TFTs.

特点和优势

Higher Purity (99.995%): Ensures minimal trace metal contamination, making it ideal for applications requiring high-purity materials.
Low Sodium Content: Specifically formulated for low sodium content (<35 ppm) to meet the stringent requirements of sensitive applications.
Controlled Particle Size: Passed through a 100 mesh sieve, ensuring most particles are less than 150 microns, which is crucial for consistent performance in various applications.

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jinghua Wu et al.
Advanced materials (Deerfield Beach, Fla.), 33(6), e2000751-e2000751 (2020-08-20)
All-solid-state lithium batteries (ASSLBs) are considered as the next generation electrochemical energy storage devices because of their high safety and energy density, simple packaging, and wide operable temperature range. The critical component in ASSLBs is the solid-state electrolyte. Among all
Hamid Mollania et al.
ACS applied materials & interfaces, 15(50), 58462-58475 (2023-12-06)
Lithium-sulfur batteries are regarded as an advantageous option for meeting the growing demand for high-energy-density storage, but their commercialization relies on solving the current limitations of both sulfur cathodes and lithium metal anodes. In this scenario, the implementation of lithium

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