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Merck
CN

940542

Lithium germanium phosphorus sulfide

(LGPS) solid electrolyte, powder

别名:

Sulfide solid electrolyte

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关于此项目

经验公式(希尔记法):
GeLi10P2S12
化学文摘社编号:
分子量:
588.78
UNSPSC代码:
12352302
NACRES:
NA.21
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等级

battery grade

质量水平

描述

application(s): battery manufacturing

方案

99.9%

表单

powder

分子量

588.69 g/mol

组成

Li10GeP2S12

密度

2.0 g/mL

应用

battery manufacturing

SMILES字符串

[Li].[S].[Ge].S=P([S-])([S-])[S-]

一般描述

Lithium germanium phosphorus sulfide solid electrolyte powder is a ceramic electrolyte with high ionic conductivity. Li10GeP2S12 (LGPS) is a white powder that crystallizes in the P42/nmc space group with three-dimensional interconnecting channels of Li+ ions that allow for fast Li+ diffusion. It belongs to the class of sulfide electrolytes and should be handled in a glovebox because LGPS is sensitive to air and moisture.

应用

Li10GeP2S12 (LGPS) is a solid electrolyte powder used in all-solid-state lithium batteries. It has an extremely high ionic conductivity of 12 mS cm–1 which is even higher than those of organic liquid electrolytes currently used in practical lithium-ion batteries. Typically, scientists pelletize (cold-press) the powder and may optionally anneal the pellet at high temperature (550 C) to enhance the ionic conductivity. LGPS is unstable against Li metal and is often used as the catholyte.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Elias Sebti et al.
Journal of the American Chemical Society, 144(13), 5795-5811 (2022-03-25)
In the pursuit of urgently needed, energy dense solid-state batteries for electric vehicle and portable electronics applications, halide solid electrolytes offer a promising path forward with exceptional compatibility against high-voltage oxide electrodes, tunable ionic conductivities, and facile processing. For this
Xiaona Li et al.
Journal of the American Chemical Society, 145(21), 11701-11709 (2023-05-17)
Inorganic solid-state electrolytes (SSEs) have gained significant attention for their potential use in high-energy solid-state batteries. However, there is a lack of understanding of the underlying mechanisms of fast ion conduction in SSEs. Here, we clarify the critical parameters that

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