ALD00002
Li-Quinoline Ligand
别名:
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline
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关于此项目
经验公式（希尔记法）:
C14H15NO
化学文摘社编号:
分子量:
213.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Form:
solid
Quality Level
InChI
1S/C14H15NO/c1-9-7-8-12-10(2)11-5-3-4-6-13(11)15-14(12)16-9/h3-6,9H,7-8H2,1-2H3
SMILES string
CC1=C2C(OC(C)CC2)=NC3=C1C=CC=C3
InChI key
ZENOEMLZOZWVRD-UHFFFAOYSA-N
form
solid
reaction suitability
reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation
mp
143-147 °C
Application
Ligand can be used in the presence of Pd(TFA)2 (Aldrich 299685) to promote C-H activation of β-Aryl-α-amino acids. This product has shown to be optimal with a 2:1 ratio of Ligand:Pd Source for several examples reported by the Yu group.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
相关内容
Yu program focuses on efficient C–H bond activation for drug synthesis, using simple starting materials.
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