ALD00108
3,6-双（甲硫基）-1,2,4,5-四嗪
≥95% (HPLC)
别名:
3,6-Bis(methylthio)-s-tetrazine, NSC 674352, s-Tetrazine
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关于此项目
经验公式（希尔记法）:
C4H6N4S2
化学文摘社编号:
分子量:
174.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
3,6-双（甲硫基）-1,2,4,5-四嗪, ≥95% (HPLC)
InChI
1S/C4H6N4S2/c1-9-3-5-7-4(10-2)8-6-3/h1-2H3
SMILES string
CSC1=NN=C(SC)N=N1
InChI key
ROUDTSAXQIBBFZ-UHFFFAOYSA-N
assay
≥95% (HPLC)
form
powder
mp
82-87 °C
storage temp.
−20°C
Quality Level
Application
3,6-Bis(methylthio)-1,2,4,5-tetrazine can be used as a versatile building block in the inverse elecron demand hetero Diels-Alder reactions. The Boger Research Group has reported this powerful approach in the synthesis of alkaloids.
It can also used to synthesize:
It can also used to synthesize:
- Substituted indoles and indolines derivatives by sequential [4+2] cycloaddition reactions.
- 3-(Methylthio)-6-(4-morpholinyl)-1,2,4,5-tetrazine by aromatic nucleophilic substitution reaction.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
3, 6-Diphenyl-1, 2, 4, 5-tetrazine
Boger DL, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 65(26), 9120-9124 (2001)
Total synthesis of Amaryllidaceae alkaloids utilizing sequential intramolecular heterocyclic azadiene Diels- Alder reactions of an unsymmetrical 1, 2, 4, 5-tetrazine
Boger DL and Wolkenberg SE
The Journal of Organic Chemistry, 65(26), 9120-9124 (2000)
Triphenylamine/tetrazine based ?-conjugated systems as molecular donors for organic solar cells
Quinton C, et al.
New. J. Chem., 39(12), 9700-9713 (2015)
商品
Inverse electron demand Diels-Alder reactions enable total synthesis of natural products with heteroaromatic ring systems.
相关内容
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