B13055
苯乙醛酸
97%
别名:
苯乙酮酸, 苯甲酰甲酸
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线性分子式:
C6H5COCOOH
化学文摘社编号:
分子量:
150.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-278-7
Beilstein/REAXYS Number:
606718
MDL number:
Assay:
97%
Form:
crystals
InChI key
FAQJJMHZNSSFSM-UHFFFAOYSA-N
InChI
1S/C8H6O3/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5H,(H,10,11)
SMILES string
OC(=O)C(=O)c1ccccc1
assay
97%
form
crystals
mp
62-65 °C (lit.)
Quality Level
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Application
苯乙醛酸可作为前驱体用于合成：
- 邻乙酰乙酰苯胺，使用 Pd 催化剂进行乙酰苯胺的脱羧邻酰化。
- 通过高真空闪速热解合成苯羟基碳。
- 使用草酸铌铵（ANO）作为催化剂与邻胺苯硫酚发生反应，合成 2-芳基苯并噻唑。
- 在草酸铌铵催化剂存在时，通过邻氨基苯酚处理合成 3-芳基-2H-苯并[b][1,4]苯并恶嗪-2-酮。
- 通过苯并噻唑的过硫酸钾（K2S2O8）-介导氧化缩合合成 2-芳基苯并噻唑。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Niobium-promoted reaction of ?-phenylglyoxylic acid with ortho-functionalized anilines: synthesis of 2-arylbenzothiazoles and 3-aryl-2 H-benzo [b][1, 4] benzoxazin-2-ones
Penteado F, et al.
Green Chemistry, 18(24), 6675-6680 (2016)
Phenylhydroxycarbene.
Gerbig D, et al.
Journal of the American Chemical Society, 132(21), 7273-7275 (2010)
Room temperature palladium-catalyzed decarboxylative ortho-acylation of acetanilides with ?-oxocarboxylic acids.
Fang P, et al.
Journal of the American Chemical Society, 132(34), 11898-11899 (2010)
Zhi-de Zhou et al.
International journal of biological macromolecules, 47(1), 21-26 (2010-04-20)
Saccharomyces cerevisiae alcohol dehydrogenase (SCAD) was effectively immobilized on hybrid alginate-chitosan beads which are hardened with glutaraldehyde. Immobilization conditions and characterization of the immobilized enzyme were investigated. Orthogonal test design and intuitive analysis method were employed to evaluate the effects
Forest H Andrews et al.
Bioorganic chemistry, 43, 26-36 (2012-01-17)
Thiamin diphosphate (ThDP) is the biologically active form of vitamin B(1), and ThDP-dependent enzymes are found in all forms of life. The catalytic mechanism of this family requires the formation of a common intermediate, the 2α-carbanion-enamine, regardless of whether the
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