B58407
4-溴苄腈
99%
别名:
1-氰基-4-溴苯, 1-溴-4-氰基苯, 1-溴-4-苯甲腈, 4-溴氰基苯, 4-溴苯基甲腈, 4-溴苯氰酸酯
质量水平
方案
99%
表单
solid
沸点
235-237 °C (lit.)
mp
110-115 °C (lit.)
SMILES字符串
Brc1ccc(cc1)C#N
InChI
1S/C7H4BrN/c8-7-3-1-6(5-9)2-4-7/h1-4H
InChI key
HQSCPPCMBMFJJN-UHFFFAOYSA-N
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应用
4-溴苯甲腈被用于通过光诱导芳香 Finkelstein 碘化反应合成 4-碘苯甲腈。也可用作芳基卤化物的测试化合物，用于开发芳基卤化物与苯基硼酸之间 Suzuki 交叉偶联的更绿色的反应条件。
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
Takato Mitsudome et al.
Chemical science, 11(26), 6682-6689 (2020-09-22)
The study of metal phosphide catalysts for organic synthesis is rare. We present, for the first time, a well-defined nano-cobalt phosphide (nano-Co2P) that can serve as a new class of catalysts for the hydrogenation of nitriles to primary amines. While
Photo-induced iodination of aryl halides under very mild conditions.
Li L
Nature Protocols, 11(10), 1948-1948 (2016)
A new air and moisture stable robust bio?polymer based palladium catalyst for highly efficient synthesis of biaryl compounds.
Baran T
Applied Organometallic Chemistry, 32(2) (2018)
Magnetic nanoparticle?tethered Schiff base?palladium (II): Highly active and reusable heterogeneous catalyst for Suzuki?Miyaura cross?coupling and reduction of nitroarenes in aqueous medium at room temperature.
Manjunatha K
Applied Organometallic Chemistry (2018)
Po-Hsuan Hsu et al.
Nanomaterials (Basel, Switzerland), 10(9) (2020-09-10)
Gold nanoclusters (AuNCs) and liquid crystals (LCs) have shown great potential in nanobiotechnology applications due to their unique optical and structural properties. Herein, the hardcore of the 4-cyano biphenyl group for commonly used LCs of 4-cyano-4'-pentylbiphenyl (5CB) was utilized to
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