C5106
乙氧甲酰基亚甲基三苯基膦
95%
别名:
(乙氧基羰基亚甲基)三苯基磷烷, 乙基(三苯基膦)乙酸酯
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关于此项目
线性分子式:
(C6H5)3P=CHCO2CH2CH3
化学文摘社编号:
分子量:
348.37
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-151-7
Beilstein/REAXYS Number:
754639
MDL number:
产品名称
乙氧甲酰基亚甲基三苯基膦, 95%
InChI key
IIHPVYJPDKJYOU-UHFFFAOYSA-N
InChI
1S/C22H21O2P/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,2H2,1H3
SMILES string
CCOC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
assay
95%
form
crystals
reaction suitability
reaction type: C-C Bond Formation
mp
128-130 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
乙氧甲酰基亚甲基三苯基膦是一种Horner-Wittig试剂，常用于 Horner−Wadsworth−Emmons(HWE)反应。它可用作 (−)-奥司他韦、 (+)-nakadomarin A和(−)-dictyostatin等化合物全合成的反应试剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
The first total synthesis of nakadomarin A
Nagata T, et al.
Journal of the American Chemical Society, 125(25), 7484-7485 (2003)
Total synthesis of (−)-dictyostatin
O'Nei GW and Phillips AJ
Journal of the American Chemical Society, 128(16), 5340-5341 (2006)
High-yielding synthesis of the anti-influenza neuraminidase inhibitor (−)-oseltamivir by two ?one-pot? sequences
Ishikawa H, et al.
Chemistry?A European Journal , 16(42), 12616-12626 (2010)
Nucleophilicity parameters for phosphoryl-stabilized carbanions and phosphorus ylides: Implications for wittig and related olefination reactions
Appel R, et al.
Journal of the American Chemical Society, 131(2), 704-714 (2008)
Scope and limitation of the reactions of 3-imino derivatives of pentane-2, 4-diones with organophosphorus reagents
Boulos LS, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 187(6), 697-710 (2012)
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